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Key Documents

COO/COA

(S)-(+)-1-Phenyl-1,2-ethanediol

Name: (<I>S</I>)-(+)-1-Phenyl-1,2-ethanediol
Brand: ALDRICH

99%

Synonym(s):

(+)-Styrene glycol, (S)-(+)-Phenylethylene glycol

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About This Item

Linear Formula:

HOCH₂CH(C₆H₅)OH

CAS Number:

25779-13-9

Molecular Weight:

138.16

Beilstein/REAXYS Number:

3196197

MDL number:

MFCD00066256

UNSPSC Code:

12352002

PubChem Substance ID:

24858237

NACRES:

NA.22

assay

99%

optical activity

[α]18/D +66°, c = 1 in chloroform

mp

64-67 °C (lit.)

SMILES string

OC[C@@H](O)c1ccccc1

InChI

1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m1/s1

InChI key

PWMWNFMRSKOCEY-MRVPVSSYSA-N

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

320.0 °F - closed cup

flash_point_c

160.00 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)

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Simultaneous determination of phenylglyoxylic acid, mandelic acid, styrene glycol and hippuric acid in primary culture of rat hepatocytes incubate by high-performance liquid chromatography.

Jin-Zhao Wang et al.

Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)

A simple HPLC method for the simultaneous determination of phenylglyoxylic acid (PGA), mandelic acid (MA), styrene glycol (SG) and hippuric acid (HA) in cell culture medium was developed. Analysis was performed on a C(18) column with a mobile phase composed

[Construction of an enzyme-coupled system consisting of (R)- and (S)-specific carbonyl reductases for one-step preparation of (S)-1-phenyl-1,2-ethanediol].

Rongzhen Zhang et al.

Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)

To prepare (S)-1-phenyl-1,2-ethanediol by a one-step method, we constructed an enzyme coupled system consisting of (R)- and (S)-specific carbonyl reductases in Escherichia coli. The genes coding (R)- and (S)-specific carbonyl reductases from Candida parapsilosis were inserted into a co-expression vector

Enantioconvergent production of (R)-1-phenyl-1,2-ethanediol from styrene oxide by combining the Solanum tuberosum and an evolved Agrobacterium radiobacter AD1 epoxide hydrolases.

Li Cao et al.

Biotechnology and bioengineering, 94(3), 522-529 (2006-02-25)

Soluble epoxide hydrolase (EH) from the potato Solanum tuberosum and an evolved EH of the bacterium Agrobacterium radiobacter AD1, EchA-I219F, were purified for the enantioconvergent hydrolysis of racemic styrene oxide into the single product (R)-1-phenyl-1,2-ethanediol, which is an important intermediate

Block copolymers of ethylene oxide and phenyl glycidyl ether: micellization, gelation, and drug solubilization.

Pablo Taboada et al.

Langmuir : the ACS journal of surfaces and colloids, 21(12), 5263-5271 (2005-06-01)

Three triblock copolymers of ethylene oxide and phenyl glycidyl ether, type E(m)G(n)E(m), where G = OCH2CH(CH2OC6H5) and E = OCH2CH2, were synthesized and characterized by gel-permeation chromatography, matrix-assisted laser desorption ionization time-of-flight mass spectrometry, and NMR spectroscopy. Their association properties

Enhancement of Candida parapsilosis catalyzing deracemization of (R,S)-1-phenyl-1,2-ethanediol to its (S)-enantiomer by a highly productive "two-in-one" resin-based in situ product removal strategy.

Qingsen Hu et al.

Bioresource technology, 101(21), 8461-8463 (2010-06-25)

In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and product removal (ISSFPR) methodology. The resin H103 was selected and used to keep the

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