259667
Methyl p-toluate
≥99%
Synonym(s):
(Methyl 4-methylbenzoate)
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About This Item
Linear Formula:
CH3C6H4CO2CH3
CAS Number:
Molecular Weight:
150.17
Beilstein/REAXYS Number:
1100609
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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vapor density
4.7 (vs air)
vapor pressure
1 mmHg ( 39 °C)
assay
≥99%
form
solid
autoignition temp.
932 °F
expl. lim.
9.5 %
bp
103-104 °C/15 mmHg (lit.)
mp
32-35 °C (lit.)
SMILES string
COC(=O)c1ccc(C)cc1
InChI
1S/C9H10O2/c1-7-3-5-8(6-4-7)9(10)11-2/h3-6H,1-2H3
InChI key
QSSJZLPUHJDYKF-UHFFFAOYSA-N
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General description
The anaerobic oxidation of methyl p-toluate by cobalt(III) in acetic acid has been investigated.
Application
Methyl p-toluate has been employesd as catalyst to investigate the effect of internal/external donor pair in high-yield catalysts for propylene polymerization.
signalword
Warning
hcodes
Hazard Classifications
Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 2
flash_point_f
No data available
flash_point_c
No data available
ppe
Eyeshields, Gloves, type N95 (US)
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Effect of the internal/external donor pair in high-yield catalysts for propylene polymerization, 2. Polymerization results.
Barbe PC, et al.
Makromol. Chem., 193(1), 229-241 (1992)
Charles E Sumner et al.
Inorganic chemistry, 47(6), 2190-2195 (2008-01-30)
The anaerobic oxidation of methyl p-toluate by cobalt(III) in acetic acid was investigated. Observed products were 4-carbomethoxybenzaldehyde (2), 4-carbomethoxybenzoic acid (3), 4-carbomethoxybenzyl acetate (1), 4,4'-dicarbomethoxybibenzyl (6), methyl 2,4-dimethylbenzoate (8), and methyl 3,4-dimethylbenzoate (9). Deuterium isotope labeling showed that 2 was
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