253189
Tris(diethylamino)phosphine
97%
Synonym(s):
Hexaethyltriamidophosphite, Hexaethyltriaminophosphine, Phosphorous acid tris(diethylamide), Tris(N,N-diethylamino)phosphine, Tris(diethylamido)phosphine, Hexaethylphosphorous triamide
About This Item
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Quality Level
assay
97%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
refractive index
n20/D 1.475 (lit.)
bp
80-90 °C/10 mmHg (lit.)
density
0.903 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
CCN(CC)P(N(CC)CC)N(CC)CC
InChI
1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
InChI key
FDIOSTIIZGWENY-UHFFFAOYSA-N
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Application
- 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.
- 1-Aminomethylisatins by treating with isatin and primary and secondary amines.
It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
138.2 °F - closed cup
flash_point_c
59 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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