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233277

Sigma-Aldrich

2,6-Difluoropyridine

99%

Synonym(s):

2,6-Difluoropyridine

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About This Item

Empirical Formula (Hill Notation):
C5H3F2N
CAS Number:
1513-65-1
Molecular Weight:
115.08
Beilstein/REAXYS Number:
1422549
EC Number:
216-152-8
MDL number:
MFCD00006227
UNSPSC Code:
12352100
PubChem Substance ID:
24853965
NACRES:
NA.22

Quality Level

100

assay

99%

form

liquid

refractive index

n20/D 1.437 (lit.)

bp

124.5 °C/743 mmHg (lit.)

density

1.268 g/mL at 25 °C (lit.)

functional group

fluoro

SMILES string

Fc1cccc(F)n1

InChI

1S/C5H3F2N/c6-4-2-1-3-5(7)8-4/h1-3H

InChI key

MBTGBRYMJKYYOE-UHFFFAOYSA-N

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General description

Lithium diisopropylamide (LDA)-mediated ortholithiations of 2,6-difluoropyridine in tetrahydrofuran at -78°C has been studied using a combination of IR and NMR spectroscopic and computational methods. Polycondensation of bistrimethylsilyl derivatives of various diphenols with 2,6-difluoropyridine in N-methylpyrrolidone in the presence of K2CO3 has been investigated.

Application

2,6-Difluoropyridine has been used in the preparation of poly(pyridine ether)s via polycondensation with silylated 1,1,1-tris(4-hydroxyphenyl)ethane.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

91.4 °F - closed cup

flash_point_c

33 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ9238
MKCQ0360
MKCJ8621
MKCG7371
MKCD0603

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Sigma-Aldrich

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Lekha Gupta et al.
The Journal of organic chemistry, 78(9), 4214-4230 (2012-12-29)
Lithium diisopropylamide (LDA)-mediated ortholithiations of 2-fluoropyridine and 2,6-difluoropyridine in tetrahydrofuran at -78 °C were studied using a combination of IR and NMR spectroscopic and computational methods. Rate studies show that a substrate-assisted deaggregation of LDA dimer occurs parallel to an
Multicyclic polyethers derived from 1, 1, 1-tris (4-hydroxyphenyl) ethane and 2, 6-dihalopyridines.
Kricheldorf HR, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 42(22), 5725-5735 (2004)
Cyclic poly (pyridine ether) s by the polycondensation of 2, 6-difluoropyridine with various diphenols.
Kricheldorf HR, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 430(20), 4781-4789 (2005)
Qianglu Lin et al.
Journal of the American Chemical Society, 139(19), 6644-6653 (2017-04-22)
The use of semiconductor nanocrystal quantum dots (QDs) in optoelectronic devices typically requires postsynthetic chemical surface treatments to enhance electronic coupling between QDs and allow for efficient charge transport in QD films. Despite their importance in solar cells and infrared

Global Trade Item Number

SKUGTIN
233277-25G4061838347572
233277-5G4061838783936

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