232777
2-(Phenylthio)ethanol
99%
Synonym(s):
2-Hydroxyethyl phenyl sulfide
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About This Item
Linear Formula:
C6H5SCH2CH2OH
CAS Number:
Molecular Weight:
154.23
Beilstein/REAXYS Number:
1860057
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
99%
form
liquid
refractive index
n20/D 1.592 (lit.)
bp
115-116 °C/2 mmHg (lit.)
density
1.143 g/mL at 25 °C (lit.)
functional group
hydroxyl
thioether
SMILES string
OCCSc1ccccc1
InChI
1S/C8H10OS/c9-6-7-10-8-4-2-1-3-5-8/h1-5,9H,6-7H2
InChI key
KWWZHCSQVRVQGF-UHFFFAOYSA-N
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Application
2-(Phenylthio)ethanol has been used:
- in the synthesis of indole, benzofuran and benzothiophene
- for temporary masking of the thymine residue during the synthesis of sugar modified thymidine derivatives
- in the preparation of 4-[2-(phenylthio)ethoxy]phthalonitrile
Storage Class
10 - Combustible liquids
wgk_germany
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Synthesis of indole, benzofuran and benzothiophene by reaction of 2-anilinoethanol, 2-phenoxyethanol and 2-(phenylthio) ethanol on AlPO4 and Pd/AlPO4 catalysts.
Afxantidis J, et al.
J. Mol. Catal. A: Chem., 102(1), 49-58 (1995)
Synthesis, characterization and electrochemistry of a new organosoluble metal-free and metallophthalocyanines.
Biyiklioglu Z, et al.
Polyhedron, 27(6), 1707-1713 (2008)
2-(Phenylthio) ethyl as a novel two-stage base protecting group for thymidine analogues.
D'Onofrio J, et al.
Synlett, 2006(06), 845-848 null
Xichang Dong et al.
Science (New York, N.Y.), 371(6528), 507-514 (2021-01-30)
Vicinal dibromides and dichlorides are important commodity chemicals and indispensable synthetic intermediates in modern chemistry that are traditionally synthesized using hazardous elemental chlorine and bromine. Meanwhile, the environmental persistence of halogenated pollutants necessitates improved approaches to accelerate their remediation. Here
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