All Photos(4)

204854

Sigma-Aldrich

Vanadium(V) oxide

greener alternative

99.95% trace metals basis

Synonym(s):
Divanadium pentoxide, Vandia, Pentaoxodivanadium, Divanadium pentaoxide
Linear Formula:
V2O5
CAS Number:
Molecular Weight:
181.88
EC Number:
MDL number:
eCl@ss:
38180404
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.95% trace metals basis

form

powder

composition

V2O5

reaction suitability

reagent type: catalyst
core: vanadium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

mp

690 °C (lit.)

density

3.35 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

Enabling

SMILES string

O=[V](=O)O[V](=O)=O

InChI

1S/5O.2V

InChI key

GNTDGMZSJNCJKK-UHFFFAOYSA-N

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Application

Selective ammoxidation catalysts for such reactions as conversion of toluene to benzonitrile or propylene to acrylonitrile were prepared by a sol-gel method from V2O5, Sb2O3 and high purity hydrogen peroxide. Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, fromV2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

Packaging

1, 5, 25 g in glass bottle

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Muta. 2 - Repr. 2 - STOT RE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Certificate of Origin

Heng Ji et al.
Nano letters, 12(6), 2988-2992 (2012-05-15)
Vanadium dioxide (VO(2)) is a strongly correlated transition metal oxide with a dramatic metal-insulator transition at 67 °C. Researchers have long been interested in manipulating this transition via the field effect. Here we report attempts to modulate this transition in
Thomas B Starr et al.
Regulatory toxicology and pharmacology : RTP, 64(1), 155-160 (2012-07-04)
The National Toxicology Program (NTP) chronic inhalation bioassay of vanadium pentoxide (V(2)O(5)) produced "clear" evidence of lung tumors in B6C3F1 mice, but only "some" and "equivocal" evidence in male and female F344/N rats, respectively. No significant pairwise differences or trends
Junkal Gutierrez et al.
ChemSusChem, 5(12), 2323-2327 (2012-10-13)
A bacterial cellulose mat was used as a template for the fabrication of conductive photoswitchable hybrid nanopaper by the incorporation of sol-gel synthesized vanadium nanoparticles. The resulting nanopaper, prepared through a green pathway, was able to photoinduce a reversible color
Yeon Seok Kim et al.
Applied biochemistry and biotechnology, 168(5), 1143-1152 (2012-09-06)
The bactericidal activity of TiO(2) nanoparticles under visible light is very important in regards to its practical applications. In this paper, we synthesized vanadium-pentoxide-loaded TiO(2) nanoparticles (V(2)O(5)-TiO(2)) using a chemical vapor condensation method, followed by the impregnation method, and characterized
M Gruber et al.
The Journal of chemical physics, 138(9), 094704-094704 (2013-03-15)
Extended cluster models together with density-functional theory are used to evaluate geometric, energetic, and electronic properties of different adsorbate species that can occur at a vanadium oxide surface where the selective catalytic reduction (SCR) of NO in the presence of

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