195936

3-(Perfluorobutyryl)-(+)-camphor

96%

• Synonym(s): (+)-3-(Heptafluorobutyryl)-(+)-camphor, 3-(Perfluorobutyryl)-D-camphor
• Empirical Formula (Hill Notation): C₁₄H₁₅F₇O₂
• CAS Number: 51800-99-8
• Molecular Weight: 348.26
• Beilstein/REAXYS Number: 2306496
• EC Number: 257-430-9
• MDL number: MFCD00064154
• UNSPSC Code: 12352115
• PubChem Substance ID: 24851726
• NACRES: NA.22

Properties

• assay: 96%
• optical activity: [α]20/D +125°, c = 2.6 in chloroform
• refractive index: n20/D 1.421 (lit.)
• bp: 60-70 °C/0.2 mmHg (lit.)
• density: 1.218 g/mL at 25 °C (lit.)
• functional group: fluoro; ketone
• SMILES string: CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1
• InChI key: PEWOESYEGLBLNR-XGLFCGLISA-N

Description

Application

3-(Perfluorobutyryl)-(+)-camphor can be used:

• As a ligand in the synthesis of chiral europium complex for optoelectronic and photonic applications.
• As a ligand in the preparation of sodium tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) complexes applicable as chemical sensors and NMR shift reagents.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 199.4 °F - closed cup
• flash_point_c: 93 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter