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192422

Sigma-Aldrich

1-Bromotridecane

98%

Synonym(s):

Tridecyl bromide

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About This Item

Linear Formula:
CH3(CH2)12Br
CAS Number:
765-09-3
Molecular Weight:
263.26
Beilstein/REAXYS Number:
1739992
EC Number:
212-138-0
MDL number:
MFCD00000227
UNSPSC Code:
12352100
PubChem Substance ID:
24851548
NACRES:
NA.22

vapor density

9.2 (vs air)

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.459 (lit.)

bp

148-150 °C/10 mmHg (lit.)

mp

4-7 °C (lit.)

density

1.03 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCBr

InChI

1S/C13H27Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14/h2-13H2,1H3

InChI key

BFDNZQUBFCYTIC-UHFFFAOYSA-N

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Application

1-Bromotridecane was used in the synthesis of:
  • tetradecanoic acid enriched with 13C at carbons 1, 3, or 6
  • (Z)-7-henicosene
  • (Z)-(2′R)-[N-carboethoxypyrrolidine]tetradec-1-ene
  • 2,3,6,7,10,11,14,15-octaalkyloxytetrabenzo[a,d,g,jlcyclododecatetraenes (CTTV-n) containing n=4-15 methylenic units in the alkyloxy substituents

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J T Sparrow et al.
Journal of lipid research, 24(7), 938-941 (1983-07-01)
The synthesis of tetradecanoic acid enriched with 13C at carbons 1, 3, or 6 is described. The label at the carbonyl carbon was introduced by treating 1-bromotridecane with K13CN (90% enriched) to form the 13C-labeled nitrile, which upon hydrolysis yielded
Alkyloxy-substituted CTTV derivatives that exhibit columnar mesophases.
Percec V, et al.
Journal of Materials Chemistry, 1(2), 217-222 (1991)
A concise synthesis of (R)-Bgugaine, a pyrrolidine alkaloid from Arisarum vulgare.
Majik MS, et al.
J. Chem. Res. (M), 2008(3), 121-122 (2008)
B V Burger et al.
Journal of chemical ecology, 30(8), 1603-1611 (2004-11-13)
Using gas chromatography-mass spectrometry in conjunction with auxiliary techniques such as solid phase microextraction and determination of double bond positions by means of dimethyl disulfide derivatization, 45 constituents of the uropygial secretion of the green woodhoopoe, Phoeniculus purpureus, have been

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