185787

4-Chlorophenol

≥99%

• Synonym(s): 4-Chlorophenol, 4-Hydroxychlorobenzene, p-Chlorophenic acid, p-Chlorophenol
• Linear Formula: ClC₆H₄OH
• CAS Number: 106-48-9
• Molecular Weight: 128.56
• Beilstein/REAXYS Number: 507004
• EC Number: 203-402-6
• MDL number: MFCD00002318
• UNSPSC Code: 12352100
• PubChem Substance ID: 24851180
• NACRES: NA.22

Properties

• vapor pressure: 1 mmHg ( 49.8 °C)
• Quality Level: 200
• assay: ≥99%
• form: solid
• impurities: <1.0% Phenol
• bp: 220 °C (lit.)
• mp: 42-45 °C
• solubility: ethanol: soluble 50 mg/mL, clear to very slightly hazy, colorless to faintly brownish-yellow
• density: 1.306 g/mL at 25 °C (lit.)
• functional group: chloro
• SMILES string: Oc1ccc(Cl)cc1
• InChI: 1S/C6H5ClO/c7-5-1-3-6(8)4-2-5/h1-4,8H
• InChI key: WXNZTHHGJRFXKQ-UHFFFAOYSA-N

Description

General description

4-Chlorophenol undergoes dechlorination to phenol rapidly on palladized graphite electrodes. Mechanism of 4-chlorophenol oxidation has been investigated by radiolytic and photocatalytic techniques.

Application

4-Chlorophenol was used:

• As a substrate in the visible-light-induced degradation studies of phenolic compounds in an aqueous suspension of pure TiO₂.
• As a model chlorinated organic pollutant in the hydrodechlorination studies of phenols using palladium nanocrystal catalysts.
• To prepare 4-chlorocatechol, hydroquinone, and benzoquinone via photo mineralization using Degussa P25 TiO₂.

Safety Information

• pictograms: GHS05,GHS07,GHS09
• signalword: Danger
• hcodes: H302 + H312 + H332,H314,H411
• pcodes: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 2
• flash_point_f: 249.8 °F - closed cup
• flash_point_c: 121 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Gloves