185396

Tetrahydrofurfuryl alcohol

99%

• Synonym(s): NSC 15434, Tetrahydro-2-furanmethanol
• Empirical Formula (Hill Notation): C₅H₁₀O₂
• CAS Number: 97-99-4
• Molecular Weight: 102.13
• Beilstein/REAXYS Number: 102723
• EC Number: 202-625-6
• MDL number: MFCD00005372
• UNSPSC Code: 12352100
• eCl@ss: 39150702
• PubChem Substance ID: 24851135
• NACRES: NA.22

Properties

• vapor density: 3.52 (vs air)
• Quality Level: 100
• vapor pressure: 2.3 mmHg ( 39 °C)
• assay: 99%
• form: liquid
• expl. lim.: 9.7 %
• refractive index: n20/D 1.452 (lit.)
• bp: 178 °C (lit.)
• mp: −80 °C (lit.)
• solubility: acetone: miscible(lit.); alcohol: miscible(lit.); benzene: miscible(lit.); chloroform: miscible(lit.); diethyl ether: miscible(lit.); water: miscible(lit.)
• density: 1.054 g/mL at 25 °C (lit.)
• functional group: ether; hydroxyl
• SMILES string: OCC1CCCO1
• InChI: 1S/C5H10O2/c6-4-5-2-1-3-7-5/h5-6H,1-4H2
• InChI key: BSYVTEYKTMYBMK-UHFFFAOYSA-N

Description

General description

Tetrahydrofurfuryl alcohol undergoes chemoselective hydrogenolysis catalyzed by Rh/SiO₂ modified with ReO_x species to yield 1,5-pentanediol. It undergoes lanthanum-mediated Michael-type addition reaction with maleate to form alkoxybutanedioic acid.

Application

Tetrahydrofurfuryl alcohol was used as refractive-index matching solvent to ensure hard sphere suspension of silica particles for rheological measurements.

Safety Information

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H319,H360Df
• pcodes: P202 - P264 - P280 - P305 + P351 + P338 - P308 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Repr. 1B
• Storage Class: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• wgk_germany: WGK 2
• flash_point_f: 163.4 °F - closed cup
• flash_point_c: 73 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter