163015

Thallium(III) nitrate trihydrate

• Synonym(s): Thallium trinitrate, TTN
• Linear Formula: Tl(NO₃)₃ · 3H₂O
• CAS Number: 13453-38-8
• Molecular Weight: 444.44
• EC Number: 237-325-4
• MDL number: MFCD00149874
• PubChem Substance ID: 24850018
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: core: thallium; reagent type: catalyst
• mp: 102-105 °C (lit.)
• SMILES string: O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
• InChI key: ZCPIKMRXMBJLCP-UHFFFAOYSA-N

Description

Application

Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.

Packaging

25, 100 g in glass bottle

Safety Information

• Pictograms: GHS03,GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H272 - H300 + H330 - H373 - H411
• Precautionary Statements: P210 - P220 - P260 - P273 - P304 + P340 + P310 - P314
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Ox. Sol. 3 - STOT RE 2
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 2
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable