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148245

2-Methoxynaphthalene

Name: 2-Methoxynaphthalene
Brand: ALDRICH

99%

Synonym(s):

Methyl 2-naphthyl ether

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About This Item

Linear Formula:

C₁₀H₇OCH₃

CAS Number:

93-04-9

Molecular Weight:

158.20

Beilstein/REAXYS Number:

1859408

EC Number:

202-213-6

MDL number:

MFCD00004061

UNSPSC Code:

12352100

PubChem Substance ID:

24848894

NACRES:

NA.22

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Sigma-Aldrich

C70223

4-Chloropyridine hydrochloride

Quality Level

100

assay

99%

bp

274 °C (lit.)

mp

70-73 °C (lit.)

solubility

benzene: soluble
carbon disulfide: soluble
diethyl ether: soluble

density

1.064 g/mL at 25 °C (lit.)

SMILES string

COc1ccc2ccccc2c1

InChI

1S/C11H10O/c1-12-11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3

InChI key

LUZDYPLAQQGJEA-UHFFFAOYSA-N

Gene Information

human ... CYP1A2(1544)

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Application

2-methoxynaphthalene acylation was used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

pictograms

GHS07,GHS09

signalword

Warning

hcodes

H319,H411

pcodes

P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Alkali-metal-mediated manganation(II) of naphthalenes: constructing metalla-anthracene and metalla-phenanthrene structures.

Victoria L Blair et al.

Inorganic chemistry, 48(18), 8863-8870 (2009-09-15)

Alkali-metal-mediated manganation (AMMMn) reactions of the synergic base sodium monoalkyl-bisamidomanganate [(tmeda)Na(tmp)(CH(2)SiMe(3))Mn(tmp)] (1) with naphthalene, 1-methoxynaphthalene, or 2-methoxynaphthalene are reported. These novel direct manganation [Mn(II)] reactions produced the crystalline ortho-manganated naphthyl products [(tmeda)Na(tmp)(2-C(10)H(7))Mn(tmp)] (3), [(tmeda)Na(tmp){2-(1-MeOC(10)H(6))}Mn(CH(2)SiMe(3))] (4), and [(tmeda)Na(tmp){3-(2-MeOC(10)H(6))}Mn(tmp)] (5) in reasonable

Single-step delamination of a MWW borosilicate layered zeolite precursor under mild conditions without surfactant and sonication.

Xiaoying Ouyang et al.

Journal of the American Chemical Society, 136(4), 1449-1461 (2013-12-19)

Layered borosilicate zeolite precursor ERB-1P (Si/B = 11) is delaminated via isomorphous substitution of Al for B using a simple aqueous Al(NO3)3 treatment. Characterization by PXRD shows loss of long-range order, and TEM demonstrates transformation of rectilinear layers in the

Synthesis of carbon-11-labeled piperidine ring of N-[omega-(6-methoxynaphthalen-1-yl)alkyl] derivatives as new selective PET sigma1 receptor probes.

Mingzhang Gao et al.

Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 68(3), 459-465 (2010-01-12)

Carbon-11-labeled piperidine ring of N-[omega-(6-methoxynaphthalen-1-yl)alkyl] derivatives were first designed and synthesized as new selective PET sigma(1) receptor probes. The target tracers were prepared by O-[(11)C]methylation of their corresponding phenolic hydroxyl precursors using [(11)C]CH(3)OTf under basic conditions and isolated by a

Entrapment and release characteristics of 2-methoxynaphthalene from cylindrical microstructures formed from phospholipids.

R R Price et al.

Journal of microencapsulation, 10(2), 215-222 (1993-04-01)

Many natural products that exhibit biocidal activity have poor solubility in water. In order to explore the prolonged delivery of these compounds from microtubules we have utilized 2-methoxynaphthalene as a model to elucidate release characteristics of hydrophobic compounds entrapped in

Dioxygenation of naphthalene by Pseudomonas fluorescens N3 dioxygenase: optimization of the process parameters.

P Di Gennaro et al.

Biotechnology and bioengineering, 93(3), 511-518 (2005-09-30)

The bioconversion of naphthalene to the 1,2-dihydro-1,2-dihydroxy derivative was performed in good yield using an Escherichia coli recombinant strain carrying Pseudomonas fluorescens N3 dioxygenase. However, the efficiency of such transformation is affected by many process parameters, and their optimization is

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