128643
2-Pyridineethanol
98%
Synonym(s):
2-(2-Hydroxyethyl)pyridine, 2-(2-Pyridyl)ethanol
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About This Item
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Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.537 (lit.)
bp
114-116 °C/9 mmHg (lit.)
density
1.093 g/mL at 25 °C (lit.)
functional group
hydroxyl
SMILES string
OCCc1ccccn1
InChI
1S/C7H9NO/c9-6-4-7-3-1-2-5-8-7/h1-3,5,9H,4,6H2
InChI key
BXGYBSJAZFGIPX-UHFFFAOYSA-N
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General description
2-(2-pyridyl)ethanol derivatives react with the aryl and alkenyl chlorides (palladium-catalyzed reactions) that result in the substitution of the chloro moieties with a 2-pyridylmethyl group.
Application
2-Pyridineethanol was used to prepare mononuclear nickel(II) acetate.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
10 - Combustible liquids
wgk_germany
WGK 2
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Acta chimica Slovenica, 59(3), 478-483 (2013-09-26)
A new mononuclear nickel(II) acetate with 2-pyridineethanol, Ni(ac)2(2-PyEtOH)2 has been prepared. The reaction product is a mixture of two polymorphic forms that crystallize concomitantly: triclinic (PĪ) and monoclinic (P21/c). Their structures have been determined at 150 K. The molecular structure
Journal of inorganic biochemistry, 215, 111311-111311 (2020-11-29)
Gold(III) complex containing 2-pyridineethanol has been synthesized and characterized structurally by single crystal X-ray diffraction, vibrational spectroscopy, 1H NMR spectroscopy, electrochemical study, and DFT calculations. The Au(III) ion is four coordinated with one N-donor ligand (L) and three Cl anions.
Palladium-catalyzed 2-pyridylmethyl transfer from 2-(2-pyridyl)ethanol derivatives to organic halides by chelation-assisted cleavage of unstrained C(sp3 )--C(sp3) bonds.
Angewandte Chemie (International ed. in English), 46(15), 2643-2645 (2007-03-03)
Toxicology and applied pharmacology, 362, 136-149 (2018-11-06)
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