L511811

9-Mesityl-10-methylacridinium perchlorate

Aldrich^CPR

• Empirical Formula (Hill Notation): C₂₃H₂₂ClNO₄
• CAS Number: 674783-97-2
• Molecular Weight: 411.88
• MDL number: MFCD09038536
• UNSPSC Code: 12352200
• PubChem Substance ID: 329817538

Properties

• SMILES string: CC1=CC(C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.O=Cl(=O)([O-])=O
• InChI: 1S/C23H22N.ClHO4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChI key: LFMBERYWDLWXNO-UHFFFAOYSA-M

Description

Application

Metal-free, visible-light mediated catalyst used by Nicewicz (BF₄ analog) for anti-Markovnikov hydroamination and hydroetherification reactions.

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

Used by Griesbeck as a visible-light mediated oxygenation catalyst in the presence of O₂.

9-Mesityl-10-methylacridinium: An Efficient Type II and Electron-Transfer Photooxygenation Catalyst

For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Safety Information

• pictograms: GHS03,GHS07
• signalword: Warning
• hcodes: H272,H315,H319,H335
• pcodes: P210 - P220 - P261 - P264 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 3 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1B - Oxidizing hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable