762458

(R)-(DTBM-SEGPHOS^®)CuH solution

0.001 M in toluene

• Synonym(s): Hydro[(4R)-[4,4′-bi-1,3-benzodioxole]-5,5′-diylbis [bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine-P]]copper(I) solution
• Empirical Formula (Hill Notation): C₇₄H₁₀₁CuO₈P₂
• CAS Number: 872517-04-9
• Molecular Weight: 1244.08
• EC Number: 203-625-9
• UNSPSC Code: 12352300
• PubChem Substance ID: 329766975

Properties

• form: liquid
• reaction suitability: core: copper; reagent type: catalyst
• concentration: 0.001 M in toluene
• density: 0.879 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: [Cu].COc1c(cc(cc1C(C)(C)C)P(c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(c(OC)c(c7)C(C)(C)C)C(C)(C)C)c8cc(c(OC)c(c8)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/C74H100O8P2.Cu/c1-67(2,3)47-33-43(34-48(61(47)75-25)68(4,5)6)83(44-35-49(69(7,8)9)62(76-26)50(36-44)70(10,11)12)57-31-29-55-65(81-41-79-55)59(57)60-58(32-30-56-66(60)82-42-80-56)84(45-37-51(71(13,14)15)63(77-27)52(38-45)72(16,17)18)46-39-53(73(19,20)21)64(78-28)54(40-46)74(22,23)24;/h29-40H,41-42H2,1-28H3;
• InChI key: VXPZLAJMRQYNLT-UHFFFAOYSA-N

Description

General description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Safety Information

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H304,H315,H336,H361d,H373,H412
• pcodes: P201 - P210 - P273 - P301 + P310 + P331 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• target_organs: Central nervous system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 42.8 °F
• flash_point_c: 6 °C