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Professor Gary Molander

Professor Gary Molander

The central theme of the Molander group's research is the development of new synthetic methods and their application to the synthesis of organic molecules. The group's current focus is to expand and improve the cross coupling reaction of organoboron compounds. Robust, air- and water-stable potassium organotrifluoroborates (R-BF3K), are employed to carry out couplings under relatively mild conditions using non-toxic components.

Molander Group Website

Recent papers from the Molander Group

1.
Tellis JC, Primer DN, Molander GA. 2014. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis. Science. 345(6195):433-436. http://dx.doi.org/10.1126/science.1253647
2.
Molander GA, Cavalcanti LN, García-García C. 2013. Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]. J. Org. Chem.. 78(13):6427-6439. http://dx.doi.org/10.1021/jo401104y
3.
Presset M, Oehlrich D, Rombouts F, Molander GA. 2013. Copper-Mediated Radical Trifluoromethylation of Unsaturated Potassium Organotrifluoroborates. J. Org. Chem.. 78(24):12837-12843. http://dx.doi.org/10.1021/jo4023233
4.
Molander GA, Trice SLJ, Kennedy SM, Dreher SD, Tudge MT. 2012. Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid. J. Am. Chem. Soc.. 134(28):11667-11673. http://dx.doi.org/10.1021/ja303181m
5.
Molander GA, Trice SLJ, Kennedy SM. 2012. Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid. J. Org. Chem.. 77(19):8678-8688. http://dx.doi.org/10.1021/jo301642v
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DISCIPLINES

  • Organic Synthetic Chemistry
  • Catalysis

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