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重要文件

930857

Sigma-Aldrich

Ni(bpy)Cl2

greener alternative

同義詞:

[Bipyridine]nickel(II) dichloride

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About This Item

經驗公式(希爾表示法):
C10H8Cl2N2Ni
CAS號碼:
分子量::
285.78
MDL號碼:
分類程式碼代碼:
12352103
NACRES:
NA.21

形狀

powder

品質等級

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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環保替代類別

儲存溫度

−20°C

SMILES 字串

Cl[Ni]1([N]2=CC=CC=C2C3=CC=CC=[N]31)Cl

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Ni(bpy)Cl2 is a nickel catalyst used for a variety of cross-coupling reactions.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Alexis L Gabbey et al.
Organic letters, 24(17), 3173-3178 (2022-04-27)
The transition-metal-catalyzed α-arylation of secondary amides remains a synthetic challenge due to the presence of a free N-H bond. We report a strategy to synthesize secondary α-aryl amides via a Ni-catalyzed reductive arylation of redox-active N-hydroxyphthalimide (NHP) esters of malonic

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