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916129

Sigma-Aldrich

1,10-Phenanthroline nickel (ll) dichloride

同義詞:

phenNiCl2

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About This Item

經驗公式（希爾表示法）:
C12H8Cl2N2Ni
CAS號碼:
22980-76-3
分子量：:
309.80
MDL號碼:
MFCD32706956
分類程式碼代碼:
12352200
NACRES:
NA.22

形狀

powder or crystals

品質等級

100

反應適用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES 字串

[Ni].Cl.Cl.n1c2c3ncccc3ccc2ccc1

InChI

1S/C12H8N2.2ClH.Ni/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h1-8H;2*1H;

InChI 密鑰

CHVPLVVTLIMTJX-UHFFFAOYSA-N

相關類別

應用

1,10-Phenanthroline nickel (ll) dichloride is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.

其他說明

Regioselective Single-Electron Tsuji-Trost Reaction of Allylic Alcohols: A Photoredox/Nickel Dual Catalytic Approach

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number

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Zheng-Jun Wang et al.
Organic letters, 21(16), 6543-6547 (2019-08-08)
A radical-mediated functionalization of allyl alcohol derived partners with a variety of alkyl 1,4-dihydropyridines via photoredox/nickel dual catalysis is described. This transformation transpires with high linear and E-selectivity, avoiding the requirement of harsh conditions (e.g., strong base, elevated temperature). Additionally

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