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重要文件

804177

Sigma-Aldrich

SnAP 3-Spiro-(2-Pyr) M试剂

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About This Item

經驗公式(希爾表示法):
C23H48N2O3Sn
分子量::
519.35
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

折射率

n/D 1.489

密度

1.122

官能基

ether

儲存溫度

−20°C

SMILES 字串

CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C)=O)CC1)N)CCCC

InChI

1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4;3*1-3-4-2;/h4-8,12H2,1-3H3;3*1,3-4H2,2H3;

InChI 密鑰

JLZWEXDNLRNRBE-UHFFFAOYSA-N

相關類別

一般說明

The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.

應用

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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相關產品

產品號碼
描述
訂價

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3


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Saturated N-heterocyclic building blocks or SnAP Reagents are of growing importance for the convenient synthesis of medium-ring saturated N-heterocycles, including bicyclic and spirocyclic structures. SnAP reagents are stable and readily available and can be coupled with widely available aromatic, heteroaromatic, aliphatic, and glyoxylic aldehydes.

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