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Merck
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文件

754730

Sigma-Aldrich

三（2,2′-联吡啶）钌（II）六氟磷酸盐

97%

同義詞:

Ru(bpy)3(PF6)2, 钌-三（2,2′-联吡啶）二六氟磷酸盐

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About This Item

經驗公式（希爾表示法）:
C30H24F12N6P2Ru
CAS號碼:
60804-74-2
分子量：:
859.55
MDL號碼:
MFCD11042502
分類程式碼代碼:
12352103
PubChem物質ID:
329766452
NACRES:
NA.23

品質等級

100

化驗

97%

形狀

solid

反應適用性

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

雜質

(Material is not fluorescence active.)

mp

>300 °C

活化光觸媒

425 nm

吸收

13,400 at 456 nm
80,000 at 291 nm

SMILES 字串

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2

InChI 密鑰

KLDYQWXVZLHTKT-UHFFFAOYSA-N

相關類別

一般說明

三(2,2′-联吡啶)钌二(六氟磷酸)盐 (Ru(bpy)3(PF6)2)是一种导电聚合物，主要用作电化学器件中的活性层。它可促进高效低压器件形成。这种材料在3V时呈现了0.35和cd/m2的外部量子效率。

應用

Ru(bpy)3(PF6)2可用作共轭聚合物，用于开发基于发光电化学电池的器件，如发光二极管(LED)。它还被用作OLED/传感器研究的高效三重态发射极。

产品可与我们的光反应器系列一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析證明 (COA)

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Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Wesley R Browne et al.
Journal of the American Chemical Society, 125(7), 1706-1707 (2003-02-13)
The excited-state properties of the transition metal complexes tris(2,2'-bipyridine) ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) are examined using picosecond time-resolved luminescence spectroscopy. For both complexes, direct observation of a short-lived high-energy emission with a lifetime of less than 4 ps is reported.
Direct measurement of the electric-field distribution in a light-emitting electrochemical cell
Slinker JD, et al.
Testing, 6(11), 894-894 (2007)
Valentina Leandri et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2
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