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904767

Sigma-Aldrich

[Ru(phen)3]Cl2

≥95%

同義詞:

氯化二氯三（1,10-菲咯啉）钌（II）

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About This Item

經驗公式（希爾表示法）:
C36H24Cl2N6Ru
CAS號碼:
23570-43-6
分子量：:
712.59
MDL號碼:
MFCD00061374
分類程式碼代碼:
12352101
NACRES:
NA.22

化驗

≥95%

形狀

powder or crystals

反應適用性

core: ruthenium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

SMILES 字串

[Ru+2]951([NH]%10=C%11C%12=[NH]9C=CC=C%12C=CC%11=CC=C%10)([NH]6=C7C8=[NH]5C=CC=C8C=CC7=CC=C6)[NH]2=C3C4=[NH]1C=CC=C4C=CC3=CC=C2.[Cl-].[Cl-]

InChI

1S/3C12H8N2.2ClH.Ru/c3*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;;;/h3*1-8H;2*1H;/q;;;;;+2/p-2

InChI 密鑰

UWXWBVKIJZGXQL-UHFFFAOYSA-L

相關類別

應用

[Ru(phen)3]Cl2是一种环金属化钌络合物，可用于可见光介导的光催化有机转化。

产品可与我们的光反应器系列配合使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他說明

光催化技术聚焦

可见光介导的乙烯基硼酸酯的脱羧自由基加成反应：快速获得氨基硼酸酯

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number
MKCP6084
MKCN3490

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Tanmay Chatterjee et al.
The Journal of organic chemistry, 81(16), 6995-7000 (2016-06-22)
A simple and practical method for the synthesis of substituted oxazoles has been developed using readily available α-bromoketones and benzylamines by visible-light photocatalysis at room temperature. The process, which requires 1 mol % of [Ru(bpy)3]Cl2 photocatalyst with K3PO4 and CCl3Br
Chelsea A Huff et al.
The Journal of organic chemistry, 81(16), 6980-6987 (2016-06-18)
We report the development of a method for room-temperature C-H hydroxymethylation of heteroarenes. A key enabling advance in this work was achieved by implementing visible light photoredox catalysis that proved to be applicable to many classes of heteroarenes and tolerant
Adam Noble et al.
Angewandte Chemie (International ed. in English), 57(8), 2155-2159 (2018-01-10)
The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single-electron reduction of an α-boryl radical intermediate to the
Jun Chen et al.
Chemical communications (Cambridge, England), 54(50), 6780-6783 (2018-02-06)
A visible light-driven photocatalytic generation of sulfonamidyl radicals, and application to intramolecular alkene hydroamination, has been accomplished, providing a mild and efficient approach to various functionalized isoxazolidines. The success of this protocol is based on the strategy of oxidative deprotonation

Global Trade Item Number

庫存單位GTIN
904767-100MG
904767-250MG

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