跳轉至內容
Merck
全部照片(2)

重要文件

704946

Sigma-Aldrich

氯(2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯基)[2-(2-氨基乙基苯基)]钯(II) - 甲基--叔丁基醚加合物

同義詞:

(2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯基)[2-(2-氨基乙基苯基)]氯化钯(II) - 甲基-叔-丁基醚加合物, (SPhos) 钯(II) 苯乙胺氯化物(1:1 MTBE 溶剂化物)

登入查看組織和合約定價


About This Item

線性公式:
C34H45ClNO2PPd · CH3OC4H9
分子量::
760.72
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

solid

品質等級

特點

generation 1

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

160-170 °C

官能基

phosphine

SMILES 字串

COC(C)(C)C.NCCc1ccccc1[Pd]Cl.COc2cccc(OC)c2-c3ccccc3P(C4CCCCC4)C5CCCCC5

InChI

1S/C26H35O2P.C8H10N.C5H12O.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1

InChI 密鑰

CLLOZWOLUBODPC-UHFFFAOYSA-M

應用

法律資訊

用法以美国专利 6307087 和 6395916 为准。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務