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Sigma-Aldrich

1,3,5-三氮杂-7-磷杂三环[3.3.1.13.7]癸烷

97%

同義詞:

1,3,5-三氮杂-7-磷代金刚烷, NSC 266642, PTA

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About This Item

經驗公式（希爾表示法）:
C6H12N3P
CAS號碼:
53597-69-6
分子量：:
157.15
MDL號碼:
MFCD00154905
分類程式碼代碼:
12352005
PubChem物質ID:
329761745
NACRES:
NA.22

化驗

97%

形狀

solid

反應適用性

reagent type: ligand
reaction type: Hydroformylations
reagent type: ligand
reaction type: Hydrogenations
reagent type: ligand
reaction type: Morita-Baylis-Hillman Reactions
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

244-250 °C

官能基

phosphine

SMILES 字串

C1N2CN3CN1CP(C2)C3

InChI

1S/C6H12N3P/c1-7-2-9-3-8(1)5-10(4-7)6-9/h1-6H2

InChI 密鑰

FXXRPTKTLVHPAR-UHFFFAOYSA-N

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相關類別

一般說明

在空气中稳定的有机催化剂，可用于 Baylis-Hillman 转化

應用

  • The molecular mechanisms of antimetastatic ruthenium compounds explored through DIGE proteomics.：该研究通过差异凝胶电泳(DIGE)蛋白质组学研究钌化合物的抗转移作用。分析了钌络合物中的1,3,5-三氮杂-7-磷杂金刚烷及其生物作用，说明它的潜在抗癌性(Guidi et al., 2013)。
  • Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes.：该研究详述含有1,3,5-三氮杂-7-磷杂金刚烷的新型银络合物的合成，评估它们的抗菌和抗增殖活性，说明该化合物可用于生物医学领域(Pettinari et al., 2011)。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number
MKCM3391
MKCG8059
MKBZ3979V
MKBW9651V
MKBL5832V

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存取文件庫

Phillips, A. D.; Gonsalvi, L. et al.
Coordination Chemistry Reviews, 248, 955-955 (2004)
William D J Tremlett et al.
Journal of inorganic biochemistry, 199, 110768-110768 (2019-07-30)
Organometallic compounds based on bioactive ligand systems have shown promising antiproliferative properties. The use of 8-hydroxyquinoline and its derivatives as bioactive ligands resulted in organometallic complexes with potent anticancer activity, but they lack aqueous solubility for further development. We report
He, Z. et al
Advanced Synthesis & Catalysis, 368, 413-413 (2006)
Leila Tabrizi et al.
Dalton transactions (Cambridge, England : 2003), 48(2), 728-740 (2018-12-19)
The new cyclometalated ruthenium(ii) complex, [Ru(CCC-Nap)(Ibu)(PTA)] was designed and synthesized using ibuprofen (Ibu), 1,3,5-triaza-7-phosphaadamantane (PTA) and CCC-pincer containing naproxen moiety (CCC-Nap) as ligands. The compounds were fully characterized by elemental analysis, FT-IR, multinuclear (1H, 13C, and 31P) NMR spectroscopy, and
Christopher S Wilson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(50), 11593-11603 (2020-06-11)
Dinuclear metallodrugs offer much potential in the development of novel anticancer chemotherapeutics as a result of the distinct interactions possible with bio-macromolecular targets and the unique biological activity that can result. Herein, we describe the development of isostructural homo-dinuclear OsII
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文章

Trialkylphosphine for Morita-Baylis Hillman Reactions

The use of amines and phosphines in nucleophilic catalysis is well precedented; however, arguably one of the severe limitations with respect to exploiting the more nucleophilic, yet less basic, phosphine in this regard is its air sensitivity.

相關內容

Trialkylphosphine for Morita-Baylis Hillman Reactions

He and co-workers have demonstrated the use of the known cage-like, air-stable trialkylphosphine, 1,3,5-triaza-7-phosphaadamantane (PTA), in organocatalysis, and specifically in the Morita-Baylis-Hillman (MBH) reaction

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