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695459

Sigma-Aldrich

1,3,5,7-四甲基-6-苯基-2,4,8-三氧-6-磷金刚烷

97%

同義詞:

1,3,5,7-四甲基-8-苯基-2,4,6-三氧-8-磷酸三环 [3.3.1.1 3,7 ] 癸烷, meCgPPh

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About This Item

經驗公式（希爾表示法）:
C16H21O3P
CAS號碼:
97739-46-3
分子量：:
292.31
分類程式碼代碼:
12352005
PubChem物質ID:
329761744
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

mp

106-111 °C

官能基

phosphine

SMILES 字串

CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2

InChI

1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3

InChI 密鑰

AVVSJWUWBATQBX-UHFFFAOYSA-N

相關類別

應用

使用1,3,5,7-四甲基-6-苯基-2,4,8-三恶-6-磷酰金刚烷：
  • 作为配体合成配合物用于氢甲酰化反应催化。
  • 用于通过分子内环化羰基化反应催化二苯并b,f][1,4]]氧氮杂卓-11(10H)-酮和3-甲基-3,4-二氢香豆素的合成。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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分析證明 (COA)

Lot/Batch Number
SHBJ8427
SHBJ3444
SHBH5553V
SHBG7553V
SHBF9423V

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存取文件庫

Diastereoselective and Branched-Aldehyde-Selective Tandem Hydroformylation-Hemiaminal Formation: Synthesis of Functionalized Piperidines and Amino Alcohols
Pittaway R, et al.
Organic Letters, 19(11), 2845-2848 (2017)
PdI2-Catalyzed Regioselective Cyclocarbonylation of 2-Allyl Phenols to Dihydrocoumarins
Ame?zquita-Valencia M and Alper H
Organic Letters, 16(22), 5827-5829 (2014)
Synthesis of Dibenzo [b, f][1, 4] oxazepin-11 (10 H)-ones via Intramolecular Cyclocarbonylation Reactions Using PdI2/Cytop 292 as the Catalytic System
Yang Q, et al.
The Journal of Organic Chemistry, 75(18), 6297-6299 (2010)
Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium (I) hydroformylation catalysts
Baber RA, et al.
Dalton Transactions, 6, 1079-1085 (2005)

文章

Trialkylphosphine for Morita-Baylis Hillman Reactions

The use of amines and phosphines in nucleophilic catalysis is well precedented; however, arguably one of the severe limitations with respect to exploiting the more nucleophilic, yet less basic, phosphine in this regard is its air sensitivity.

相關內容

Trialkylphosphine for Morita-Baylis Hillman Reactions

He and co-workers have demonstrated the use of the known cage-like, air-stable trialkylphosphine, 1,3,5-triaza-7-phosphaadamantane (PTA), in organocatalysis, and specifically in the Morita-Baylis-Hillman (MBH) reaction

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