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Merck
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重要文件

695149

Sigma-Aldrich

DTBPF

同義詞:

1,1′-双(二叔丁基膦)二茂铁

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About This Item

經驗公式(希爾表示法):
C26H44FeP2
CAS號碼:
分子量::
474.42
MDL號碼:
分類程式碼代碼:
12350000
PubChem物質ID:
NACRES:
NA.22

形狀

solid

品質等級

反應適用性

reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reagent type: ligand
reaction type: Indole Forming Reactions

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

73-75 °C

官能基

phosphine

SMILES 字串

[Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C

InChI

1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;

InChI 密鑰

FPLSJBJGQLJLSV-UHFFFAOYSA-N

應用

形成二烯络合物;羰基插入;环加成;还原和脱氧。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

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Sergeyev, S.; Hesse, M.
Synlett, 8, 1313-1313 (2002)
Sean H Wiedemann et al.
The Journal of organic chemistry, 71(5), 1969-1976 (2006-02-25)
The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur consecutively with heterocycle dehydrogenation in the presence of a Rh(I)/PCy3/HCl catalyst. The reaction was used
Darbasie, N. D.; Schnatter, W. F. K. et al.
Tetrahedron Letters, 47, 963-963 (2004)
Anthony J Pearson et al.
Journal of the American Chemical Society, 125(44), 13326-13327 (2003-10-30)
A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three transformations (complexation, isomerization, and cyclization) were realized in a single operation. The product of this

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