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About This Item
經驗公式（希爾表示法）:
C32H35N4P
CAS號碼:
分子量：:
506.62
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
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化驗
97%
形狀
solid
反應適用性
reaction type: Cross Couplings
reagent type: ligand
reaction type: Amidations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Coupling Reactions
mp
169-173 °C
官能基
phosphine
SMILES 字串
CC(C)(C)P(c1ccnn1-c2c(nn(-c3ccccc3)c2-c4ccccc4)-c5ccccc5)C(C)(C)C
InChI
1S/C32H35N4P/c1-31(2,3)37(32(4,5)6)27-22-23-33-36(27)30-28(24-16-10-7-11-17-24)34-35(26-20-14-9-15-21-26)29(30)25-18-12-8-13-19-25/h7-23H,1-6H3
InChI 密鑰
PTXJGGGNGMPMBG-UHFFFAOYSA-N
應用
用于卤代芳烃（包括氯代芳烃）钯催化胺化的非专有配体。当钯源为 Pd2(dba)3 (328774) 时效果最佳。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
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Organic letters, 11(4), 947-950 (2009-01-31)
A general and practical method for the preparation of unsymmetrically substituted ureas has been developed utilizing palladium-catalyzed amidation. Both aryl bromides and chlorides, as well as heteroaryl chlorides, have been coupled to aryl, benzyl, and aliphatic ureas by using a
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Organic letters, 11(1), 233-236 (2008-11-28)
The bis-pyrazole phosphine ligand BippyPhos is effective for the palladium-catalyzed cross-coupling of hydroxylamines with aryl bromides, chlorides, and iodides. Reactions proceed smoothly at 80 degrees C in toluene in the presence of Cs(2)CO(3) to give synthetically versatile N-arylhydroxylamine products in
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Saravanan Gowrisankar et al.
Journal of the American Chemical Society, 132(33), 11592-11598 (2010-08-03)
An efficient procedure for palladium-catalyzed coupling reactions of (hetero)aryl bromides and chlorides with primary aliphatic alcohols has been developed. Key to the success is the synthesis and exploitation of the novel bulky di-1-adamantyl-substituted bipyrazolylphosphine ligand L6. Reaction of aryl halides
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