跳轉至內容
Merck
全部照片(1)

文件

483877

Sigma-Aldrich

5-（三氟甲基）二苯并噻吩三氟甲磺酸盐

97%

同義詞:

S-（三氟甲基）二苯并噻吩三氟甲磺酸盐

登入查看組織和合約定價
全部照片(1)

About This Item

經驗公式（希爾表示法）:
C14H8F6O3S2
CAS號碼:
129946-88-9
分子量：:
402.33
MDL號碼:
MFCD00236132
分類程式碼代碼:
12352101
PubChem物質ID:
24871923
NACRES:
NA.22

化驗

97%

mp

150 °C (lit.)

SMILES 字串

[O-]S(=O)(=O)C(F)(F)F.FC(F)(F)[S+]1c2ccccc2-c3ccccc13

InChI

1S/C13H8F3S.CHF3O3S/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)8(5,6)7/h1-8H;(H,5,6,7)/q+1;/p-1

InChI 密鑰

QXXHXTRTGZBOGD-UHFFFAOYSA-M

相關類別

應用

  • Pd（II）-催化的三氟甲基化
  • 离子液体中的亲电子三氟甲基化
  • 使用Umemoto试剂和铜催化剂通过末端炔烃的三氟甲基化立体选择性制备三氟甲基炔烃

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。

已經擁有該產品？

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

客戶也查看了

Slide 1 of 1

1 of 1

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6 ≥95%

Sigma-Aldrich

902217

Ir[dFFppy]2-(4,4′-dCF3bpy)PF6

Copper-catalyzed trifluoromethylation of terminal alkynes using Umemoto's reagent
Luo, D.-F.; et al.
Tetrahedron Letters, 53, 2769-2772 (2012)
Ionic liquids as new media for electrophilic trifluoromethylation reactions
Pegot, B.; et al.
Journal of Fluorine Chemistry, 134, 156-159 (2012)
Jun Xu et al.
Journal of the American Chemical Society, 133(39), 15300-15303 (2011-09-15)
An unprecedented type of reaction for Cu-catalyzed trifluoromethylation of terminal alkenes is reported. This reaction represents a rare instance of catalytic trifluoromethylation through C(sp(3))-H activation. It also provides a mechanistically unique example of Cu-catalyzed allylic C-H activation/functionalization. Both experimental and
Xing-Guo Zhang et al.
Journal of the American Chemical Society, 134(29), 11948-11951 (2012-07-12)
A Pd(II)-catalyzed trifluoromethylation of ortho C-H bonds with an array of N-arylbenzamides derived from benzoic acids is reported. N-Methylformamide has been identified as a crucial promoter of C-CF(3) bond formation from the Pd center. X-ray characterization of the C-H insertion

我們的科學家團隊在所有研究領域都有豐富的經驗，包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務