416908

B-Iodo-9-BBN 溶液

1.0 M in hexanes

• 同義詞: 9-碘-9-硼杂二环[3.3.1]壬烷 溶液
• 經驗公式（希爾表示法）: C₈H₁₄BI
• CAS號碼: 70145-42-5
• 分子量：: 247.91
• MDL號碼: MFCD00192226
• 分類程式碼代碼: 12352101
• PubChem物質ID: 24866083
• NACRES: NA.22

屬性

• 形狀: liquid
• 品質等級: 100
• 濃度: 1.0 M in hexanes
• 密度: 0.816 g/mL at 25 °C
• SMILES 字串: IB1C2CCCC1CCC2
• InChI: 1S/C8H14BI/c10-9-7-3-1-4-8(9)6-2-5-7/h7-8H,1-6H2/t7-,8+
• InChI 密鑰: YAYIUFDUYUYPJC-OCAPTIKFSA-N

描述

一般說明

B-Iodo-9-BBN is a boron-based organic compound that is commonly used as a reagent in organic synthesis for the iodoboration of alkynes, enolboration, the demethylation of phenol methyl ethers, and synthesis of boron-containing compounds.

應用

B-Iodo-9-BBN solution (1.0 M in hexanes) can be used as a Lewis acid in the selective synthesis of δ-keto esters via a Michael-type addition reaction to α,β-unsaturated ketones.

安全資訊

• 象形圖: GHS02,GHS08,GHS07,GHS09
• 訊號詞: Danger
• 危險聲明: H225,H304,H315,H336,H361f,H372,H411
• 防範說明: P202 - P210 - P273 - P301 + P310 - P303 + P361 + P353 - P331
• 危險分類: Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3
• 標靶器官: Central nervous system, Nervous system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -9.4 °F - closed cup
• 閃點（°C）: -23 °C - closed cup