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Key Documents

459496

Sigma-Aldrich

9-硼双环[3.3.1]壬烷 溶液

0.4 M in hexanes

同義詞:

9-BBN

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About This Item

經驗公式(希爾表示法):
C8H15B
CAS號碼:
分子量::
122.02
Beilstein:
605509
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

品質等級

反應適用性

reagent type: reductant

濃度

0.4 M in hexanes

bp

68-70 °C

密度

0.691 g/mL at 25 °C

SMILES 字串

B1C2CCCC1CCC2

InChI

1S/C8H15B/c1-3-7-5-2-6-8(4-1)9-7/h7-9H,1-6H2/t7-,8+

InChI 密鑰

FEJUGLKDZJDVFY-OCAPTIKFSA-N

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應用

烯烃保护基团†

反应物用于:
  • 线性SPPS合成泛素衍生物
  • 铜催化有机硼化合物与伯烷基卤化物和拟卤化物发生交叉偶联反应
  • 将烯烃分子内插入钯-氮键
  • 制备(膦酰基乙酰基)鸟氨酸以研究对酵母中精氨酸生物合成基因的影响
  • Hetero-Diels-Alder反应合成螺环生物碱

訊號詞

Danger

危險分類

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3 - Water-react 1

標靶器官

Central nervous system, Nervous system

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Solid-phase synthesis is a powerful tool for achieving high-throughput chemistry. This review discusses recent diverse examples from my group: the solid-phase synthesis of unsymmetrical guanidines, polymer-supported versions of cyclooctadiene and 9-BBN, a triflate-like linker, the synthesis of tetrahydro-beta-carbolines by the
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1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity
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We report a spectroscopic and microscopic investigation of the synthesis of gold nanoparticles (AuNPs) with average sizes of less than 5 nm. The slow reduction and AuNP formation processes that occur by using 9-borabicyclo[3.3.1]nonane (9-BBN) as a reducing agent enabled

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