推薦產品
品質等級
反應適用性
reaction type: Grignard Reaction
濃度
2.0 M in diethyl ether
密度
0.947 g/mL at 25 °C
SMILES 字串
CCCCC[Mg]Br
InChI
1S/C5H11.BrH.Mg/c1-3-5-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
InChI 密鑰
ZXWGTPYWPZGZPT-UHFFFAOYSA-M
應用
Pentylmagnesium bromide solution is a Grignard reagent that can be used in the preparation of:
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
- Alkanes via Ni or Cu-catalyzed cross-coupling reaction with alkyl fluorides.
- Hydroxypiperidinones via the addition-cyclization-deprotection process of aldimines.
It can also be used as a reagent to synthesize a key intermediate by olefin alkylation in the total synthesis of alkaloid, (+)-hyperaspine , and surface alkylation of H-terminated Si (111), by Si-C bond formation.
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
-40.0 °F - closed cup
閃點（°C）
-40 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
A six-step asymmetric synthesis of (+)-hyperaspine
Comins DL and Sahn JJ
Organic Letters, 7(23), 5227-5228 (2005)
Ronia Chung-Tin Sham et al.
Environment international, 137, 105567-105567 (2020-02-23)
The occurrence of triphenyltin (TPT) compounds, a highly toxic antifouling biocide, has been documented in marine environments and organisms all over the world. While some studies showed that marine mammals can be used as sentinel organisms to evaluate the pollution
Ni-or Cu-catalyzed cross-coupling reaction of alkyl fluorides with Grignard reagents
Terao J, et al.
Journal of the American Chemical Society, 125(19), 5646-5647 (2003)
Muhammad Waqar Ashraf et al.
Bulletin of environmental contamination and toxicology, 98(6), 811-816 (2017-04-14)
In the present work, data on the levels of hazardous Organotin compounds in eight commercially important fish species, caught from Arabian Gulf, has been reported. Highest levels of tributyltin (TBT) (98.5 ng/g dry weight) were detected in Epinephelus Tauvina whereas minimum
Alkylation of Si surfaces using a two-step halogenation/Grignard route
Bansal A, et al.
Journal of the American Chemical Society, 118(30), 7225-7226 (1996)
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