推薦產品
蒸汽密度
3 (vs air)
品質等級
形狀
liquid
成份
halide, ~0.05 M
濃度
1.6 M in diethyl ether
密度
0.732 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
[Li]C
InChI
1S/CH3.Li/h1H3;
InChI 密鑰
DVSDBMFJEQPWNO-UHFFFAOYSA-N
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一般說明
甲基锂是一种有机锂试剂，主要用于去质子化和作为甲基阴离子的来源。它是一种强碱和强亲核体。
應用
在手性铜催化剂存在下，甲基锂水溶液（1.6 M 乙醚中）已用于烯丙基亲电试剂的不对称烯丙基烷基化反应。该方案导致具有高度对映选择性的三级和四级立体中心的 C-C 键形成。它也可用于在（ - ） - 鹰爪豆碱作为手性配体存在下与6,7-二甲氧基-3,4-二氢异喹啉反应而用于合成（ - ） - 猪毛菜碱。
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
1.4 °F - closed cup
閃點（°C）
-17 °C - closed cup
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文章
Reagents for C–C Bond Formation
We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.
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