255025

己基溴化镁 溶液

2.0 M in diethyl ether

• 同義詞: 1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
• 線性公式: CH₃(CH₂)₅MgBr
• CAS號碼: 3761-92-0
• 分子量：: 189.38
• Beilstein: 3535624
• MDL號碼: MFCD00000046
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24855279
• NACRES: NA.22

屬性

• 反應適用性: reaction type: Grignard Reaction
• 濃度: 2.0 M in diethyl ether
• 密度: 0.965 g/mL at 25 °C
• SMILES 字串: CCCCCC[Mg]Br
• InChI: 1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
• InChI 密鑰: SFXUWNMDTWQSHE-UHFFFAOYSA-M

描述

一般說明

Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.

應用

Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.

安全資訊

• 象形圖: GHS02,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H260,H302,H314,H336
• 防範說明: P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• 標靶器官: Central nervous system
• 安全危害: EUH019
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: -40.0 °F - closed cup
• 閃點（°C）: -40 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter