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重要文件

630551

Sigma-Aldrich

(2-乙基己基)溴化镁 溶液

1.0 M in diethyl ether

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About This Item

經驗公式(希爾表示法):
C8H17BrMg
CAS號碼:
分子量::
217.43
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

反應適用性

reaction type: Grignard Reaction

品質等級

濃度

1.0 M in diethyl ether

密度

0.863 g/mL at 25 °C

SMILES 字串

CCCCC(CC)C[Mg]Br

InChI

1S/C8H17.BrH.Mg/c1-4-6-7-8(3)5-2;;/h8H,3-7H2,1-2H3;1H;/q;;+1/p-1

InChI 密鑰

NDCJRLBSQQDNOO-UHFFFAOYSA-M

應用

(2-Ethylhexyl)magnesium bromide (Grignard reagent) can be used in the synthesis of:       
  • 3-ethyl-N,N-dimethyl-1-(pyridin-2-yl)heptan-1-amine, a pyridyl amine ligand, which is used in the polymerization of olefins.   
  •  Diphenylbis(2-ethylhexyl) germane from diphenylgermanium dichloride by Grignard addition reaction.       
  • Dichloro (dodecyl) 2-ethylhexylsilane, a key intermediate that is used in the preparation of silafluorene-based copolymers.

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

-13.0 °F - closed cup

閃點(°C)

-25 °C - closed cup


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分析證明 (COA)

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Chinna D Bathula et al.
Journal of nanoscience and nanotechnology, 14(8), 6002-6007 (2015-05-06)
A series of silafluorene-based copolymers, poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (P1), poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-2,5-bis-(thiophene-2-yl)thiazolo [5,4-d]thiazole] (P2), and poly[9-(2-ethylhexyl)-9-dodecyl-silafluorene-2,7-diyl-alt-5,5-(5',8'-di-2-thienyl-2,3-bis(4-octyloxyl)phenyl)quinoxaline] (P3), were synthesized and used as donor materials in polymer solar cells (PSCs). The optical, electrochemical, and photovoltaic properties of the copolymers were investigated. The results indicate that
A low band gap co-polymer of dithienogermole and 2, 1, 3-benzothiadiazole by Suzuki polycondensation and its application in transistor and photovoltaic cells
Fei Z, et al.
Journal of Materials Chemistry, 21(40), 16257-16263 (2011)

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