跳轉至內容
Merck
全部照片(2)

Key Documents

230200

Sigma-Aldrich

硼氢化锂 溶液

2.0 M in THF

同義詞:

Lithium boron hydride, Lithium hydroborate

登入查看組織和合約定價


About This Item

線性公式:
LiBH4
CAS號碼:
分子量::
21.78
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

反應適用性

reagent type: reductant

濃度

2.0 M in THF

密度

0.896 g/mL at 25 °C

SMILES 字串

[Li+].[H][B-]([H])([H])[H]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI 密鑰

UUKMSDRCXNLYOO-UHFFFAOYSA-N

尋找類似的產品? 前往 產品比較指南

應用

反应物用于:
  • 镓、铟、铼和锌三(巯基咪唑基)氢硼酸配合物的制备
  • 机械化学复分解反应
  • 非催化水解制氢
  • 大型金单层保护簇的生长
  • 阴离子取代反应
  • 脱氢反应
硼氢化锂溶液 (2M in THF) 分别用于 5-亚苄基-2,4-噻唑烷二酮类和 5-亚苄基-4-氧代-2-噻唑烷二酮类的还原,并分别生成 5-苄基-2,4-噻唑烷二酮类和 5-苄基-4-氧代-2-噻唑烷二酮类。

包裝

推荐将25毫升安全/密封瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system, Respiratory system

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 2

閃點(°F)

-0.4 °F - closed cup

閃點(°C)

-18 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


從最近期的版本中選擇一個:

分析證明 (COA)

Lot/Batch Number

未看到正確版本?

如果您需要一個特定的版本,您可以透過批號來尋找特定憑證。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Regiospecific reduction of 5-benzylidene-2, 4-thiazolidinediones and 4-oxo-2-thiazolidinethiones using lithium borohydride in pyridine and tetrahydrofuran.
Giles RG
Tetrahedron, 56(26), 4531-4537 (2000)
G Váradi et al.
International journal of peptide and protein research, 43(1), 29-30 (1994-01-01)
For solid-phase peptide synthesis, 2,4-dimethoxy-4'-hydroxbenzhydrol linker was prepared via lithium borohydride reduction of 2,4-dimethoxy-4'-hydroxybenozophenone. The potassium salt of the linker was coupled to chloromethylpolystyrene. This method proved to be better than use of the cesium salt. This new synthesis gave
Barbara Milani et al.
Dalton transactions (Cambridge, England : 2003), (34)(34), 4659-4663 (2008-11-26)
Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome
N P Arbatskiĭ et al.
Bioorganicheskaia khimiia, 26(1), 51-60 (2000-05-12)
By the example of fetuin and a blood-group-specific mucin from porcine stomach, we showed that, under conditions of reductive degradation of glycoproteins with LiBH4-LiOH in 70% aqueous tert-butyl alcohol, the reduction and cleavage of amide bonds occur much faster than
Prabhat Arya et al.
Journal of combinatorial chemistry, 6(1), 54-64 (2004-01-13)
A diversity-oriented solution and solid-phase synthesis of tetrahydroquinoline-based tricyclic derivatives has been achieved from enantiomerically pure, natural product-like bicyclic scaffold. The solution synthesis of enantiopure bicyclic scaffold was developed by asymmetric hetero Michael reaction. Our approach for the synthesis of

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務