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Key Documents

T76201

Sigma-Aldrich

氧杂环丁烷

97%

同義詞:

三甲撑氧

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About This Item

經驗公式(希爾表示法):
C3H6O
CAS號碼:
分子量::
58.08
Beilstein:
102382
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

5.09 psi ( 20 °C)

品質等級

化驗

97%

折射率

n20/D 1.388-1.396
n20/D 1.392 (lit.)

bp

50 °C (lit.)

密度

0.893 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C1COC1

InChI

1S/C3H6O/c1-2-4-3-1/h1-3H2

InChI 密鑰

AHHWIHXENZJRFG-UHFFFAOYSA-N

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應用

  • Trimethylene oxide is a strained cyclic ether which can be used to replace carbonyl / gem-dimethyl groups during molecular modelling of bioactive molecules.
  • It can be incorporated in various bioactive molecule and drug substances for its improved physicochemical properties, via novel C-H activation methods.
  • Trimethylene oxide can also be used in the synthesis of poly(trimethylene oxide) and related polymer electrolytes.

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-4.0 °F - closed cup

閃點(°C)

-20 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


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分析證明 (COA)

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Photocatalytic Synthesis of Oxetane Derivatives by Selective C-H Activation.
Ravelli D, et al.
Advanced Synthesis & Catalysis, 356(13), 2781-2786 (2014)
Radical ?-C? H Hydroxyalkylation of Ethers and Acetal.
Yoshimitsu T, et al.
The Journal of Organic Chemistry, 70(6), 2342-2345 (2005)
Radical addition of ethers to alkenes under dioxygen catalyzed by N-hydroxyphthalimide (NHPI)/Co(OAc)2.
Hirano K, et al.
Tetrahedron Letters, 43(20), 3617-3620 (2002)
Role of polar side chains in Li+ coordination and transport properties of polyoxetane-based polymer electrolytes.
Sai R, et al.
Physical Chemistry Chemical Physics, 19(7), 5185-5194 (2017)
Cross-linked poly (oxetane) matrix for polymer electrolyte containing lithium ions.
Tsutsumi H, et al.
Solid State Ionics, 262, 761-764 (2014)

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