推薦產品
品質等級
化驗
≥97.0% (AT)
形狀
solid
mp
191 °C (dec.) (lit.)
SMILES 字串
ClP(=O)(N1CCOC1=O)N2CCOC2=O
InChI
1S/C6H8ClN2O5P/c7-15(12,8-1-3-13-5(8)10)9-2-4-14-6(9)11/h1-4H2
InChI 密鑰
KLDLRDSRCMJKGM-UHFFFAOYSA-N
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應用
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride was used in the preparation of hexadepsipeptide.
其他說明
活化羧基，合成酰胺、酯、肽 的试剂
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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J. Cabre et al.
Synthesis, 413-413 (1984)
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Hexadepsipeptide 2, the precursor of Hirsutellide A (1), was synthesized in an overall yield of 45% from N-Boc-Me-Gly via three coupling reactions using dicyclohexylcarbodiimide (DCC), O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyl- uronium hexafluorophosphate (HATU) and bis(2-oxo-3-oxazolidinyl)phosphinic chloride (BOP-Cl), respectively.
R.D. Tung et al.
Journal of the American Chemical Society, 107, 4342-4342 (1985)
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