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178756

Sigma-Aldrich

叠氮磷酸二苯酯

97%

同義詞:

DPPA, 二苯基磷酰叠氮化物

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About This Item

線性公式:
(C6H5O)2P(O)N3
CAS號碼:
26386-88-9
分子量：:
275.20
Beilstein:
2058967
EC號碼:
247-644-0
MDL號碼:
MFCD00001987
分類程式碼代碼:
12352302
PubChem物質ID:
24850766
NACRES:
NA.22

品質等級

200

化驗

97%

形狀

liquid

反應適用性

reaction type: click chemistry

折射率

n20/D 1.551 (lit.)

bp

157 °C/0.17 mmHg (lit.)

密度

1.277 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

[N-]=[N+]=NP(=O)(Oc1ccccc1)Oc2ccccc2

InChI

1S/C12H10N3O3P/c13-14-15-19(16,17-11-7-3-1-4-8-11)18-12-9-5-2-6-10-12/h1-10H

InChI 密鑰

SORGEQQSQGNZFI-UHFFFAOYSA-N

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相關類別

應用

氢氧叠氮催化有机叠氮化物粗制备

在改良Curtis重排反应中，用作合成连接氨基甲酸酯和尿素键的低聚糖合成试剂
四苯基钴卟啉催化的烯烃氮杂环化反应。
在制备大环内酰胺和醛糖还原酶抑制剂过程中，用作活化剂。

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

233.6 °F - closed cup

閃點（°C）

112 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析證明 (COA)

Lot/Batch Number
MKCJ1322
MKCG7023
MKCF8399
MKBZ0923V
MKBW9677V

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The Journal of Organic Chemistry, 71, 6665-6665 (2006)
B L Mylari et al.
Journal of medicinal chemistry, 34(3), 1011-1018 (1991-03-01)
Ethyl 1-benzyl-3-hydroxy-2(5H)-oxopyrrole-4-carboxylate (1, EBPC) is a potent and specific inhibitor of aldose reductase. It was greater than 4000X more potent in its inhibition of rat lens aldose reductase than the closely related rat or pig kidney aldehyde reductase, thus making
D. Sawada, et al.,
Tetrahedron, 64, 8780-8788 (2008)
Qiaoya Li et al.
European journal of medical research, 22(1), 48-48 (2017-11-23)
This study aimed to investigate the therapeutic effects of 5-fluorouracil (5-FU)-loaded nanobubbles irradiated with low-intensity, low-frequency ultrasound in nude mice with hepatocellular carcinoma (HCC). A transplanted tumor model of HCC in nude mice was established in 40 mice, which were
Tetrahedron Letters, 31, 6469-6469 (1990)
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Hydroazidation Catalyst

The chemistry of organoazides is exceedingly rich, since the azide functionality reacts with electrophiles, nucleophiles, and dipolarophiles, with or without the extrusion of dinitrogen. Common place transformation such as Staudinger reductions or ligations, Cu(I)-catalyzed Huisgen cycloadditions (of the “click” reaction family), Curtius or Schmidt rearrangents, nitrene reactions, or imine formation via aza-Wittig reactions all necessitate organoazide precursors or intermediates

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