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130850

Sigma-Aldrich

3-丁炔-1-醇

97%

同義詞:

3-Butynol

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About This Item

線性公式:
HC≡CCH2CH2OH
CAS號碼:
927-74-2
分子量：:
70.09
Beilstein:
773710
EC號碼:
213-161-9
MDL號碼:
MFCD00002955
分類程式碼代碼:
12352100
eCl@ss:
39020335
PubChem物質ID:
24847980
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.441 (lit.)

bp

128.9 °C (lit.)

mp

−63.6 °C (lit.)

密度

0.926 g/mL at 25 °C (lit.)

官能基

hydroxyl

SMILES 字串

OCCC#C

InChI

1S/C4H6O/c1-2-3-4-5/h1,5H,3-4H2

InChI 密鑰

OTJZCIYGRUNXTP-UHFFFAOYSA-N

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相關類別

一般說明

3-丁炔-1-醇的燃烧和汽化焓用静态燃烧量热法和相关气相色谱法测量 。

應用

3-丁炔-1-醇用于制备马氏加成物 。
合成元用于制备含氧杂环 和受保护的s-羟基-L-异亮氨酸酯
在钯催化偶合 β-tetrionic酸溴化物的研究中，使用炔基底物，可使生成炔基取代呋喃酮的产量很高。

象形圖

FlameExclamation mark
GHS02,GHS07

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

96.8 °F - closed cup

閃點（°C）

36 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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分析證明 (COA)

Lot/Batch Number
MKBB6950
07030DJ
19101EE
17901EE
15318DD

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存取文件庫

Deniz Dogruer et al.
Bioorganic & medicinal chemistry letters, 14(2), 523-526 (2003-12-31)
The binding of a series pyridylbutynylamines 6 was examined at alpha4beta2 nACh receptors. Structural modifications, comparing 6 with pyridyl ethers 2, did not consistently result in parallel effects on receptor affinity, suggesting possible differences in their modes of binding. Furthermore
Sumod A Pullarkat et al.
Inorganic chemistry, 45(18), 7455-7463 (2006-08-29)
Alcohol functionalized diphosphine ligands with chirality residing on the carbon backbone were prepared using a novel two-stage asymmetric synthetic methodology from the corresponding terminal alkynols. Under mild conditions, the alkynols, 3-butyn-1-ol and 2-propyn-1-ol, were subjected to direct hydrophosphination to give
Tetrahedron Letters, 48, 105-105 (2007)
Kopf, Henning; Pietraszuk. et al.
Organometallics, 25(10), 2533-2546 (2006)
Johanna E Grimm et al.
Journal of agricultural and food chemistry, 67(20), 5838-5846 (2019-05-06)
An aroma extract dilution analysis applied to the volatiles isolated from jackfruit ( Artocarpus heterophyllus Lam.) pulp by solvent extraction and solvent-assisted flavor evaporation resulted in the detection of 48 odorants with flavor dilution (FD) factors between 1 and ≥8192.
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文章

Functionalized Alkynes

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C–C coupling; and cycloadditions

Functionalized Alkynes

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C–C coupling; and cycloadditions

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