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Key Documents

122440

Sigma-Aldrich

噻蒽

97%

同義詞:

二苯并二硫代二噁烷

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About This Item

經驗公式(希爾表示法):
C12H8S2
CAS號碼:
分子量::
216.32
Beilstein:
83046
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

bp

364-366 °C (lit.)

mp

151-155 °C (lit.)

溶解度

DMF: soluble
H2O: insoluble

SMILES 字串

S1c2ccccc2Sc3ccccc13

InChI

1S/C12H8S2/c1-2-6-10-9(5-1)13-11-7-3-4-8-12(11)14-10/h1-8H

InChI 密鑰

GVIJJXMXTUZIOD-UHFFFAOYSA-N

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一般說明

在大孔沸石和中孔铝硅酸盐催化剂存在时,噻蒽可通过液相丁基化反应生成丁基衍生物。在过氧化氢和木质素酶作为来自黄孢原毛平革菌的催化剂存在时,噻蒽经氧化可生成噻蒽单亚砜

應用

噻蒽已被用于研究蒽、菲和芴的几种固体含氮、硫和氧的杂环衍生物的水溶性。它已被用于测定1-己基-3-甲基咪唑(三氟甲基磺酰基)酰亚胺和超临界二氧化碳中几种含硫芳烃的分配系数

相關產品

產品號碼
描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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Pavel Karásek et al.
Journal of chromatography. A, 1140(1-2), 195-204 (2006-12-05)
We report the aqueous solubilities of phenanthrene and several solid three-ring aromatic heterocycles (phenanthridine, acridine, phenazine, thianthrene, phenothiazine, phenoxathiin, phenoxazine, carbazole, dibenzofuran, dibenzothiophene, and 4,6-dimethyldibenzothiophene) at temperatures ranging from 313K to the solute melting point and at a pressure of
Acid zeolites as catalysts in organic reactions.< i> tert</i>-Butylation of anthracene, naphthalene and thianthrene.
Armengol E, et al.
Applied Catalysis A: General, 149(2), 411-423 (1997)
Distribution of sulfur-containing aromatics between [hmim][Tf2N] and supercritical CO2: a case study for deep desulfurization of oil refinery streams by extraction with ionic liquids.
Planeta J, et al.
Green Chemistry, 8(1), 70-77 (2006)
R P Schreiner et al.
Applied and environmental microbiology, 54(7), 1858-1860 (1988-07-01)
The oxidation of heterocyclic sulfur compounds reported to be part of the macrostructure of coal and petroleum was investigated. The oxidation of thianthrene solubilized in 10% dimethylformamide to thianthrene monosulfoxide in the presence of hydrogen peroxide was catalyzed by the
Saowapak Kaenkaew et al.
Journal of molecular modeling, 16(2), 243-253 (2009-07-10)
The structures of thiacalix[2]thianthrene, p-tert-butylthiacalix[2]thianthrene and their complexes with Zn(2+), Cd(2+) and Hg(2+) were obtained using B3LYP/LanL2DZ and HF/LanL2DZ calculations. The structures of the most stable conformers of thiacalix[2]thianthrene and p-tert-butylthiacalix[2]thianthrene optimized at either the B3LYP/LanL2DZ or HF/LanL2DZ level are

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