903981

2,3,7,8-Tetrafluorothianthrene-S-oxide

≥95%

• 同義詞: 2,3,7,8-Tetrafluorothianthrene-5-oxide, Fluorinated sulfoxide-based thianthrene reagent, Ritter C-H functionalization linchpin, TFT S-oxide, TFT-reagent
• 經驗公式（希爾表示法）: C₁₂H₄F₄OS₂
• CAS號碼: 2320491-72-1
• 分子量：: 304.28
• MDL號碼: MFCD32062467
• 分類程式碼代碼: 12352101
• NACRES: NA.22
• 形狀: solid
• 化驗: ≥95%

屬性

• 化驗: ≥95%
• 形狀: solid
• mp: 253 °C
• 官能基: fluoro; sulfoxide; thioether
• 儲存溫度: −20°C
• SMILES 字串: Fc1cc2c(cc1F)Sc3c(cc(c(c3)F)F)[S]2=O
• InChI: 1S/C12H4F4OS2/c13-5-1-9-11(3-7(5)15)19(17)12-4-8(16)6(14)2-10(12)18-9/h1-4H

描述

應用

2,3,7,8-Tetrafluorothianthrene-S-oxide (TFT S-oxide) is a fluorinated sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation with TFT S-oxide proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations.
The nonfluorinated thianthrene S-oxide is also available as catalog# 903973 for all arenes more electron-rich than anisole.

其他說明

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

In the Pipeline: New Chemistry, Making New Things

法律資訊

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable