925446

5-Vinylthianthrenium tetrafluoroborate

≥95%

• 同義詞: Vinyl-TT
• 經驗公式（希爾表示法）: C₁₄H₁₁BF₄S₂
• CAS號碼: 2703016-98-0
• 分子量：: 330.17
• 分類程式碼代碼: 12352108
• NACRES: NA.22

屬性

• 品質等級: 100
• 化驗: ≥95%
• 形狀: powder
• 反應適用性: reaction type: C-C Bond Formation
• mp: 110-112 °C
• 官能基: thioether
• 儲存溫度: −20°C
• SMILES 字串: [F-][B+3]([F-])([F-])[F-].S1C=2C=CC=CC2[S+](C=C)C=3C=CC=CC13
• InChI: 1S/C14H11S2.BF4/c1-2-16-13-9-5-3-7-11(13)15-12-8-4-6-10-14(12)16;2-1(3,4)5/h2-10H,1H2;/q+1;-1
• InChI 密鑰: FXHBWPNFHMRFKM-UHFFFAOYSA-N

描述

應用

5-Vinylthianthrenium tetrafluoroborate is a crystalline, shelf-stable vinylating reagent developed by the Ritter Lab. Despite the great functionality of the vinyl group for diversification of target compounds, the selective installation of this moeity has remained challenging. 5-Vinylthianthrenium tetrafluoroborate can perform this otherwise challenging transformation with a broad scope of substrate, including the N-vinylation of heterocycles, vinylation of aryl boronic acids, and the annulation of cyclic and heterocyclic substrates. Additionally, this reagent can be used to enable palladium catalyzed cross-coupling reactions. The functionality of 5-vinylthianthrenium tetrafluoroborate enables the usage of vinyl groups as a versatile tool for further functionalization of many substrates and is a functional tool for many snythetic pathways.

其他說明

Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable