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Merck

399124

Sigma-Aldrich

高锰酸钾

ACS reagent, ≥99.0%, low in mercury

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About This Item

经验公式(希尔记法):
KMnO4
CAS号:
分子量:
158.03
EC號碼:
MDL號碼:
分類程式碼代碼:
12352312
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

化驗

≥99.0%

形狀

solid

反應適用性

reagent type: oxidant

雜質

≤0.005% N compounds
≤0.2% insolubles

pH值

7.2-9.7 (20 °C, 20 g/L)

溶解度

water: soluble 63.8 g/L at 20 °C(lit.)
acetone: soluble(lit.)
methanol: soluble(lit.)

負離子痕跡

chloride, chlorate (as Cl-): ≤0.005%
sulfate (SO42-): ≤0.02%

正離子痕跡

Hg: ≤0.05 ppm

SMILES 字串

[K+].[O-][Mn](=O)(=O)=O

InChI

1S/K.Mn.4O/q+1;;;;;-1

InChI 密鑰

VZJVWSHVAAUDKD-UHFFFAOYSA-N

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一般說明

Potassium permanganate (PP, KMnO4) is a dark violet colored crystalline solid. It is a strong oxidizing agent used in the oxidation of a wide range of organic compounds. PP is commonly used as a disinfectant to treat external infections in aquaculture. Corncobs pretreated with alkaline potassium permanganate solution showed high carbohydrate recovery due to the increased enzymatic hydrolysis of lignocellulose. The acidic potassium permanganate chemiluminescence detection has been employed for the detection of cannabinoids.

應用

Potassium permanganate was used in the preparation of layered MnO2 which may be employed as cathodic material in lithium secondary batteries.
It may be used as an oxidant in:
  • The reduction of polycyclic aromatic hydrocarbons found in coal tar pitches (CTPs).
  • Oxidation of decabromodiphenyl ether in sulfuric acid medium.
  • Oxidative cleavage of oximes to the corresponding carbonyl compounds potassium permanganate supported on kieselguhr.
  • Oxidation of progestagens.
适用于非均相氧化。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2 - Repr. 2 - Skin Corr. 1 - STOT RE 2 Inhalation

標靶器官

Brain

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Reducing polycyclic aromatic hydrocarbons content in coal tar pitch by potassium permanganate oxidation and solvent extraction.
Wang W, et al.
Journal of Environmental Chemical Engineering, 3(3), 1513-1521 (2015)
Preparation of layered MnO2 via thermal decomposition of KMnO4 and its electrochemical characterizations.
Kim, S.H. et al.
Chemistry of Materials, 11(3), 557-563 (1999)
Oxidative Degradation of Decabromodiphenyl Ether (BDE 209) by Potassium Permanganate: Reaction Pathways, Kinetics, and Mechanisms Assisted by Density Functional Theory Calculations.
Shi J, et al.
Environmental Science & Technology, 49(7), 4209-4217 (2015)
Degradation of progestagens by oxidation with potassium permanganate in wastewater effluents.
Fayad PB, et al.
Chemistry Central Journal, 7, 84-84 (2013)
Screening of cannabinoids in industrial-grade hemp using two-dimensional liquid chromatography coupled with acidic potassium permanganate chemiluminescence detection.
Pandohee J, et al.
Journal of Separation Science, 38(12), 2024-2032 (2015)

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