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Merck

D35457

Sigma-Aldrich

N,N-二苄基羟胺

98%

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About This Item

线性分子式:
(C6H5CH2)2NOH
CAS号:
分子量:
213.28
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

crystals

mp

125-128 °C (lit.)

SMILES 字串

ON(Cc1ccccc1)Cc2ccccc2

InChI

1S/C14H15NO/c16-15(11-13-7-3-1-4-8-13)12-14-9-5-2-6-10-14/h1-10,16H,11-12H2

InChI 密鑰

GXELTROTKVKZBQ-UHFFFAOYSA-N

應用

N,N-Dibenzylhydroxylamine, upon oxidation, yields N-benzyl-α-phenylnitrone, which can undergo cycloaddition reaction with suitable dipolarophiles. It can be used to synthesize N,N,O-trisubstituted hydroxylamines and arylamines.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Synthesis of N,N,O-Trisubstituted Hydroxylamines by Stepwise Reduction and Substitution of O-Acyl N, N-Disubstituted Hydroxylamines.
Dhanju S and Crich D
Organic Letters, 18(8), 1820-1823 (2016)
Chemoselective Ligation of Peptide Phenyl Esters with N?Terminal Cysteines.
Fang GM, et al.
Chembiochem, 11(8), 1061-1065 (2010)
Recent developments in nitrone chemistry: some novel transformations.
Yang J
Synlett, 23(16), 2293-2297 (2012)
Synthesis of Arylamines via Aminium Radicals.
Svejstrup TD, et al.
Angewandte Chemie (International Edition in English), 56(47), 14948-14952 (2017)
Mechanistic studies lead to dramatically improved reaction conditions for the Cu-catalyzed asymmetric hydroamination of olefins.
Bandar JS, et al.
Journal of the American Chemical Society, 137(46), 14812-14818 (2015)

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