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Merck
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695882

Sigma-Aldrich

PhDave-Phos

97%

别名:

2-二苯基膦-2′-(N,N-二甲基氨基)联苯, 2′-(二苯基膦基)-N,N′-二甲基--(1,1′-联苯)-2-胺, PhDavePhos

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About This Item

经验公式（希尔记法）:
C26H24NP
CAS号:
240417-00-9
分子量:
381.45
MDL號碼:
MFCD03094578
分類程式碼代碼:
12352116
PubChem物質ID:
329761783
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

powder

反應適用性

reaction type: Cross Couplings
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: C-C Bond Formation

mp

122-126 °C

官能基

phosphine

SMILES 字串

CN(C)c1ccccc1-c2ccccc2P(c3ccccc3)c4ccccc4

InChI

1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3

InChI 密鑰

JGFXUYLYPITYGR-UHFFFAOYSA-N

相关类别

應用

Buchwald膦配体的更多信息

二烷基联芳基膦配体常用于各种环境中的钯催化反应。

法律資訊

用法以美国专利 6307087 和 6395916 为准。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
SHBM8316
SHBJ3094
SHBG7841V
SHBG7735V
SHBF1978V

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David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses

商品

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

Buchwald Phosphine Ligands

Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

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