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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chemical science (2011-01-01)

David S Surry, Stephen L Buchwald

摘要

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this class for the most commonly encountered and practically important substrate combinations.

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Sigma-Aldrich

2-二环己基磷-2′,4′,6′-三异丙基联苯, 98%

Sigma-Aldrich

2-二环己基膦基-2′,6′-二甲氧基联苯基, 98%

Sigma-Aldrich

2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯, 98%

Sigma-Aldrich

2-(二环己基膦)3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯, 98%

Sigma-Aldrich

2-(二叔丁基膦)联苯, 97%

Sigma-Aldrich

2-二环己膦基-2′-(N,N-二甲胺)联苯, 97%

Sigma-Aldrich

tBuBrettPhos, 97%

Sigma-Aldrich

CyJohnPhos, 97%

Sigma-Aldrich

Me 4 叔丁基磷, 96%

Sigma-Aldrich

2-{双[3,5-双(三氟甲基)苯基]膦基}-3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯, 95%

Sigma-Aldrich

sSPhos

Sigma-Aldrich

tBuXPhos Pd G1

Sigma-Aldrich

2-二环己基磷-2′-甲基联苯, 97%

Sigma-Aldrich

2-二叔丁基膦-2′-(N,N-二甲氨基)联苯

Sigma-Aldrich

氯-（2-二环己基膦-2′,6'-双异丙氧基-1,1′-联苯） [2-（2-氨乙基）苯基] 钯 (Ⅱ)-甲基--叔 -丁醚加合物, 95%

Sigma-Aldrich

BrettPhos Pd G1有机钯化合物, may contain up to 1 mole equivalent of MTBE, 97%

Sigma-Aldrich

2-二环己基膦基-2′,6′-二甲氧基联苯基, 95%

Sigma-Aldrich

PhDave-Phos, 97%

Sigma-Aldrich

2-二叔丁基膦-2′-甲基联苯

Sigma-Aldrich

氯(2-二环己基膦基-2′,6′-二甲氧基-1,1′-联苯基)[2-(2-氨基乙基苯基)]钯(II) - 甲基--叔丁基醚加合物

Sigma-Aldrich

RuPhos ChemBeads