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Sigma-Aldrich

双(三氟甲烷)磺酰亚胺 锂盐

别名:

双(三氟甲基磺酰)胺 锂盐, 双三氟甲烷磺酰亚胺锂

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About This Item

线性分子式:
CF3SO2NLiSO2CF3
CAS号:
90076-65-6
分子量:
287.09
Beilstein:
6625414
EC號碼:
415-300-0
MDL號碼:
MFCD00210017
分類程式碼代碼:
12352302
PubChem物質ID:
24868486
NACRES:
NA.22

mp

234-238 °C (lit.)

SMILES 字串

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

InChI 密鑰

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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應用

双(三氟甲烷)磺酰亚胺锂盐（Li-TFSI）可用于：
  • 用作提高卟啉基有机太阳能电池电力转换效率的化学添加剂。     
  • 用作制备含咪唑核心单体离子液体的试剂，以开发聚合离子液体。
  • 通过相应三氟甲磺酸酯的阴离子复分解，制备手性咪唑鎓盐。       
  • 合成用于锂离子电池的固体聚合物电解质。 
  • 合成聚电解质可重复使用均相催化剂，可用于异戊二烯和各种亲二烯体间的Diels-Alder反应。
  • 用于制备锂电池电解液和新型稀土路易斯酸催化剂。

其他說明

关于含氟氮酸的综述，请参见 Coordination Chemistry Reviews。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

標靶器官

Nervous system

儲存類別代碼

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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分析证书(COA)

Lot/Batch Number
WXBD6926V
WXBD5956V
WXBD4557V
WXBD3621V
WXBD3221V

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Tetrahedron Letters, 45, 4429-4429 (2004)
Electrochimica Acta, 41, 2369-2369 (1996)
Amino alcohol-derived chiral ionic liquids: structural investigations toward chiral recognition
Vasiloiu M, et al.
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