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Merck

805394

Sigma-Aldrich

FK 209 Co(III) TFSI salt

别名:

三(2-(1H-吡唑-1-基)-4-丁基吡啶)钴(III)三[双(三氟甲烷)磺酰亚胺]

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About This Item

经验公式(希尔记法):
C42H45CoF18O12N12S6
分子量:
1503.17
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

98%

品質等級

形狀

powder

mp

281.5 °C (exp.)

SMILES 字串

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.CC(C)(C)C1=CC(N2N=CC=C2)=NC=C1.CC(C)(C)C3=CC=NC(N4C=CC=N4)=C3.CC(C)(C)C5=CC=NC(N6C=CC=N6)=C5.C

相关类别

一般說明

FK 209 Co(III) TFSI盐(FK 209)是一种钴(III)配合物,可以用作空穴传输材料用p型掺杂剂,使功率转换效率达9-12%。

應用

FK 209可用于诱导PCDTBT和spiro-OMeTAD的p型掺杂,用于制造效率达15-16%的钙钛矿太阳能电池(PSC)的空穴传输材料。
用这种钴配合物大幅度提高液体电解质电池的光电压,或通过固态光伏器件实现超高性能。

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Efficient perovskite photovoltaic devices using chemically doped PCDTBT as a hole-transport material.
Wong-Stringer M, et al.
Journal of Material Chemistry A, 5(30), 15714-15723 (2017)
Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films

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