所有图片(1)
About This Item
线性分子式:
C6H5CH2OCH2CHO
CAS号:
分子量:
150.17
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級
化驗
97%
形狀
liquid
包含
0.5% hydroquinone as stabilizer
折射率
n20/D 1.518 (lit.)
bp
118-120 °C/13 mmHg (lit.)
密度
1.069 g/mL at 25 °C (lit.)
官能基
aldehyde
ether
phenyl
SMILES 字串
O=CCOCc1ccccc1
InChI
1S/C9H10O2/c10-6-7-11-8-9-4-2-1-3-5-9/h1-6H,7-8H2
InChI 密鑰
NFNOAHXEQXMCGT-UHFFFAOYSA-N
一般說明
苄氧基乙醛是一种非天然醛。在存在 C2-对称性双（恶唑啉基）吡啶 Cu(II) 配合物（催化剂）的条件下，它可与甲硅烷基乙烯酮缩醛亲核试剂进行对映选择性 Mukaiyama 羟醛反应。
應用
苄氧基乙醛可用于合成以下成分：
- (3S,5S)-6-苄氧基-3,5-二羟基己酸甲酯
- (S)-5-苄氧基-4-羟基戊烷-2-酮
- 噻虫唑
苄氧基乙醛可用于通过抗体催化合成 1-脱氧-L-木酮糖。
訊號詞
Warning
危險分類
Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Formal total syntheses of Myxothiazols by three different approaches starting from benzyloxyacetaldehyde.
Backhaus D.
Tetrahedron Letters, 41(13), 2087-2090 (2000)
A short enantioselective synthesis of 1-deoxy-L-xylulose by antibody catalysis.
Shabat D, et al.
Tetrahedron Letters, 40(8), 1437-1440 (1999)
L Vidal et al.
Applied microbiology and biotechnology, 68(4), 489-497 (2005-02-24)
The glyA gene encoding a serine hydroxymethyl transferase (SHMT) with threonine aldolase activity was isolated from Streptococcus thermophilus YKA-184 chromosomal DNA. This aldolase is a pyridoxal 5'-phosphate-dependent enzyme that stereospecifically catalyzes the interconversion of L-threonine to glycine and acetaldehyde. The
C2-symmetric copper (II) complexes as chiral Lewis acids. Scope and mechanism of catalytic enantioselective aldol additions of enolsilanes to (benzyloxy) acetaldehyde.
Evans DA, et al.
Journal of the American Chemical Society, 121(4), 669-685 (1999)
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