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B8378

Sigma-Aldrich

2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole

≥99%

Synonym(s):

2-(4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole, Butyl-PBD

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About This Item

Empirical Formula (Hill Notation):
C24H22N2O
CAS Number:
Molecular Weight:
354.44
Beilstein/REAXYS Number:
1086414
EC Number:
MDL number:
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.32

assay

≥99%

form

powder

fluorescence

λex 305 nm; λem 364 nm in ethanol

OLED device performance

ITO/DTFD/PBD/Alq3/LiF/Al

  • Color: blue
  • Max. Luminance: 400 Cd/m2
  • Max. EQE: 1.6 %
  • Turn-On Voltage: 4 V

ITO/PEDOT:PSS/TPD/PVK:Ir(ppy)3 (6%)/PBD/Al
  • Color: green
  • Max. Luminance: 10000 Cd/m2

storage temp.

2-8°C

SMILES string

CC(C)(C)c1ccc(cc1)-c2nnc(o2)-c3ccc(cc3)-c4ccccc4

InChI

1S/C24H22N2O/c1-24(2,3)21-15-13-20(14-16-21)23-26-25-22(27-23)19-11-9-18(10-12-19)17-7-5-4-6-8-17/h4-16H,1-3H3

InChI key

XZCJVWCMJYNSQO-UHFFFAOYSA-N

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Application

2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole (PBD) can be used as a hole-blocking material in the fabrication of multilayer polymer light-emitting diodes to enhance the efficiency of the device. It is also used as an additive to fabricate the polyurethane (PU) based bistable nonvolatile memory devices with resistive switching characteristics. By incorporating PBD with PU, device performance showed significant improvement, with increase in ON/OFF ratio by two orders of magnitude and a long retention period of over five hours. PBD is also an organic fluorescent molecule used to prepare plastic scintillators.

Related product

Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

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Blue-light-emitting organic electroluminescence via exciplex emission based on a fluorene derivative
Li, F.; et al.
Journal of Physics D: Applied Physics, 37, 1613-1613 (2004)
Multilayer polymer light-emitting diodes by blade coating method
Tseng S-R, et al.
Applied Physics Letters, 93(15), 382-382 (2008)
Selective Metal Transfer and its Application to Patterned Multicolor Organic Light-Emitting Diodes
Lee, D.; et al.
Advanced Materials, 16, 1851 - 1854 (2011)
Dharmendar Kumar Sharma et al.
Nature communications, 10(1), 4499-4499 (2019-10-05)
Halide perovskites nanocrystals (NCs) are being explored as promising materials for optoelectronic applications, such as light-emitting devices or lasers. However, electroluminescence devices prepared from such NCs have long suffered from low efficiency and there has been no systematic study on

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