34869

Dimethyl sulfoxide

suitable for HPLC, ≥99.7%

• Synonym(s): DMSO
• Linear Formula: (CH₃)₂SO
• CAS Number: 67-68-5
• Molecular Weight: 78.13
• Beilstein/REAXYS Number: 506008
• EC Number: 200-664-3
• MDL number: MFCD00002089
• UNSPSC Code: 41116105
• PubChem Substance ID: 329755076
• NACRES: NA.21

Properties

• vapor density: 2.7 (vs air)
• Quality Level: 100
• vapor pressure: 0.42 mmHg ( 20 °C)
• assay: ≥99.7%
• form: liquid
• autoignition temp.: 573 °F
• expl. lim.: 42 %, 63 °F
• technique(s): HPLC: suitable
• impurities: ≤0.002% non-volatile matter; ≤0.2% water (Karl Fischer)
• transmittance: 270 nm, ≥20%; 280 nm, ≥50%; 300 nm, ≥80%; 350 nm, ≥98%
• refractive index: n20/D 1.479 (lit.)
• bp: 189 °C (lit.)
• mp: 16-19 °C (lit.)
• density: 1.10 g/mL (lit.)
• application(s): food and beverages
• SMILES string: CS(C)=O
• InChI: 1S/C2H6OS/c1-4(2)3/h1-2H3
• InChI key: IAZDPXIOMUYVGZ-UHFFFAOYSA-N

Description

General description

Dimethyl sulfoxide (DMSO) is a polar organic solvent. DMSO activated by various electrophiles (oxalyl chloride) has been used to oxidize various alcohols (primary, secondary, allylic, benzylic, hindered and bicyclic). Carbonyl compounds are formed as reaction products. Due to its higher stability, it has been proposed as an alternate solvent for methyl cellosolve for use in ninhydrin reaction.

Application

Suitable for HPLC, spectrophotometry, environmental testing

Caution

Supercools easily and remelts slowly at room temperature. Solidified product can be re-liquified by warming to room temperature without detriment to the product.

Other Notes

For information on dimethyl sulfoxide miscibility, please visit the following link:
Dimethyl Sulfoxide Miscibility/Immiscibility Table

Important notice

• The article number 34869-4X2.5L will be discontinued. Please order the single bottle 34869-2.5L which is physically identical with the same exact specifications.
• The article number 34869-6X1L will be discontinued. Please order the single bottle 34869-1L which is physically identical with the same exact specifications.

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Safety Information

• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 1
• flash_point_f: 188.6 °F - closed cup
• flash_point_c: 87 °C - closed cup